541-4005/01 – Praktická hydrogeochemie (PHGCH)
Gurantor department | Department of Geological Engineering | Credits | 3 |
Subject guarantor | doc. Mgr. Eva Geršlová, Ph.D. | Subject version guarantor | doc. Mgr. Eva Geršlová, Ph.D. |
Study level | undergraduate or graduate | Requirement | Compulsory |
Year | 1 | Semester | winter |
| | Study language | Czech |
Year of introduction | 2021/2022 | Year of cancellation | |
Intended for the faculties | HGF | Intended for study types | Follow-up Master |
Subject aims expressed by acquired skills and competences
Our intention is to provide a broad coverage of topics (see annotation of the course) in order to acquaint students with the basic principles of the subject taught and their practical applications.
Teaching methods
Lectures
Tutorials
Summary
The course deals with the issue of groundwater chemistry in the regime of their flow at the contact with the rock environment and in the places of their accumulation, solves the hydrogeochemical principles of groundwater for application in water management. The purpose of the course is to acquaint students with the main laws of groundwater in the rock environment, the characteristics of the rock and aquifers, with the methods of studying the chemistry of water resources, their evaluation and model predictions of their development. An integral part is the teaching of groundwater protection principles in the field of prevention (including existing legislation) and reparation of endangered resources.
Compulsory literature:
Recommended literature:
Way of continuous check of knowledge in the course of semester
Individual consultations, practical exercises with geochemical programs, solution of real examples. The course is completed by a credit from exercises and a written exam.
E-learning
Other requirements
The study of recommended literature.
Prerequisities
Subject has no prerequisities.
Co-requisities
Subject has no co-requisities.
Subject syllabus:
Thermodynamic functions. Distance from equilibrium. Rate constants, transition state theory, influence of surface area and temperature, potential barrier, dynamic equilibrium. Saturation index. Molar and mass fractions, ionic strength, equivalents. Stability diagrams (systems Si, Al, Fe, Mn, Cu, Zn, Pb - aqueous solutions, forms of occurrence, distribution and stability as a function of pH). Forms of occurrence of substances in water (true and colloidal solutions, suspensions, ions, complexes, ion pairs, organic complexes). Chemical and physical properties of water (structure, bonds, partial charges, dissolution of solid phases, dissolution of gases => partial pressure, Henry's law, dependence of Henry's constant on temperature). Carbonate system (basic components of the system, distribution coefficients, closed and open system, acid-base titrations, buffers, Gran's function). Acid-base reactions (water dissociation, pH, mass balances, electroneutrality condition, proton condition, acidity and alkalinity, methods of determination). Oxidation-reduction processes (electrochemical potentials, Nernst equation, redox potential, mixed potentials, electron activity, electrodes, Eh / pH diagrams). Organic substances (organic carbon, chemical oxygen demand, contaminants of organic origin, biodegradation, humic substances, etc.). Radioactive substances and isotopes in groundwater (separation, structure, fractionation, geochronology, etc.). Methods of hydrogeochemical data processing, geochemical programs. Practical examples.
Conditions for subject completion
Occurrence in study plans
Occurrence in special blocks
Assessment of instruction