615-0809/01 – Structure of Chemical Materials (KCHL)

Gurantor departmentDepartment of Analytic Chemistry ProcessesCredits5
Subject guarantordoc. RNDr. Ervín Kozubek, CSc.Subject version guarantordoc. RNDr. Ervín Kozubek, CSc.
Study levelundergraduate or graduate
Study languageCzech
Year of introduction2004/2005Year of cancellation2013/2014
Intended for the facultiesFMTIntended for study typesFollow-up Master
Instruction secured by
LoginNameTuitorTeacher giving lectures
KOZ60 doc. RNDr. Ervín Kozubek, CSc.
PAV57 Ing. Jiří Pavlovský, Ph.D.
VON37 Ing. Jiřina Vontorová, Ph.D.
Extent of instruction for forms of study
Form of studyWay of compl.Extent
Full-time Credit and Examination 2+2

Subject aims expressed by acquired skills and competences

To take up with possibilities of structure study. Focus on methods for inorganic, organic and structural analysis. Their application to describe the structure of chemical substances.

Teaching methods

Lectures
Tutorials
Experimental work in labs

Summary

Subject was established to upgrade some principal subjects (Inorganic and Oganic Analysis) in the field of chemical compounds structure description from either theoretic (simulation and theoretic calculations) or practical (intensification of spectral and separation methods of instrumental structural analysis) point of view.

Compulsory literature:

[1] Böhm, S., Smrčková-Voltrová, S. Strukturní analýza organických sloučenin VŠCHT, skripta, 152 s., 1995. [2] Volkenštejn, M. Struktura a vlastnosti molekul ČSAV, Praha, 722 s., 1962 [3] Papoušek, D. Základy chemické konstituce SPN, Praha 103 s., 1961. [4] Kuthan, S. Úvod do fyz.-chem.metod org. chemie SNTL, Praha 1971, 284 s. [5] Simon,W., Clerc,Thomas Structural Analysis of Organic Compounds by Spectroscopic Methods American Elsevier New York, 1971.

Recommended literature:

[1] Beiser, A. Úvod do moderní fyziky Academia Praha 1975, 628 s. [2] Leško, J., Tržil, J., Ullrych, J. Obecná chemie ES VŠB-TU, Ostrava 1997. [3] Holík, M. Čtyři lekce z NMR spektroskopie UJEP, skripta, 113 s., Brno, 1987.

Way of continuous check of knowledge in the course of semester

E-learning

Další požadavky na studenta

There are no additional requirements for students.

Prerequisities

Subject codeAbbreviationTitleRequirement
615-0803 OA Organic Analysis Recommended
9360-0001 AA Inorganic analyses Recommended

Co-requisities

Subject has no co-requisities.

Subject syllabus:

1st The theory of chemical structure. Packing arrangement of electron, the interaction between electrons, structure and power relations of atoms, models of atoms, structure and physical properties of molecules. 2nd Chemical bonding (early), and length of energy ties, with no binding electrons (Ion, ion - dipole, dipole - dipole), the links binding the electrons (and home- heteropolární, single, double and víceelektronové), the method of molecular orbits, linear combination of atomic orbits, mesomer method. Theory streamlined links (Hybridization), the main types of hybridization of sp-diagonal, trigonal sp2, tetrahedral sp3 tetragonal sp2d, hybridization sp3d, octahedral sp3d2. 3rd The chemical bonds in polyatomic molecules. Energy relations and non-flush interaction of atoms, conjugated bond, resonance energy mesomerie, electron density, order links, conjugation of simple links, the structure complex compounds. 4th The spatial structure of molecules. X-ray diffraction of crystalline substances crystal structure, interatomic distances and angles between bonds, symmetry and antisymmetry molecules, the basic principles of stereochemistry. 5th UV / VIS absorption spectra of organic molecules, the characteristic absorption belts, and the interpretation of UV-VIS spectra, correlation spectra and structures of organic compounds. 6th Rotational and vibrational spectra of polyatomic molecules and biatomických. Basics group theory and symmetry of molecules. Systematics of the point groups of symmetry. 7th Interpretation of basic functional groups of organic compounds from vibration- rotational spectra. The characteristic absorption bands of functional groups (eg C- C, C = C, C C, C = O, ...). 8th Interpretation of the Constitution of basic organic substances from vibration-rotation spectra: alkanes, alkenes, aromatic compounds, ethers, alcohols, carboxylic ... 9th NMR spectrum, the number of signals (resonance condition, shielding effect of signals environment temperature ,..), position signal (chemical shift, standards, ...) Intensity signals (depending on the core, concentration, ...) split signals (spin- spin interaction, decoupling, ...). 10th 13C, 1H NMR spectrum and range of other nuclides, the NMR measurement techniques spectra, the interpretation of NMR-spectra of different organic compounds, quantitative analysis. 11th Mass spectrum. Common fragment ions and the corresponding likelihood compounds, fragmentation mechanisms, mass spectral analysis, examples and Interpretation Service. 12th Electrical properties of molecules, dipole and electric dipole moment induction and dielectric constant, polarization and polarizability, refractive index, molar refraction. Optical properties of molecules. Refraction and dispersion of light, and molar ion refraction, light scattering, polarizability anisotropy and structure molecules. 13th Optical properties of molecules (Continued). Raman scattering, optical activity and structure of molecules. Magnetic properties of molecules in the magnetic behavior of materials field, the magnetic properties, diamagnetism and paramagnetism of atoms and molecules, nuclear and electron paramagnetic resonance, and their relationship to structure and magnetic phenomena. 14th Macromolecular compounds. Structure and physical properties macromolecules, internal rotation in polymer chains and the theory of rotating isomerism, physical and kinetic properties of macromolecules and chain stretching network structure of macromolecules.

Conditions for subject completion

Conditions for completion are defined only for particular subject version and form of study

Occurrence in study plans

Academic yearProgrammeField of studySpec.FormStudy language Tut. centreYearWSType of duty
2013/2014 (N3909) Process Engineering (3911T008) Chemical and Physical Methods of Material Testing P Czech Ostrava 2 Compulsory study plan
2012/2013 (N3909) Process Engineering (3911T008) Chemical and Physical Methods of Material Testing P Czech Ostrava 2 Compulsory study plan
2011/2012 (N3909) Process Engineering (3911T008) Chemical and Physical Methods of Material Testing P Czech Ostrava 2 Compulsory study plan
2010/2011 (N3909) Process Engineering (3911T008) Chemical and Physical Methods of Material Testing P Czech Ostrava 2 Compulsory study plan
2009/2010 (N3909) Process Engineering (3911T008) Chemical and Physical Methods of Material Testing P Czech Ostrava 2 Compulsory study plan
2008/2009 (N3909) Process Engineering (3911T008) Chemical and Physical Methods of Material Testing P Czech Ostrava 2 Compulsory study plan
2007/2008 (N3909) Process Engineering (3911T008) Chemical and Physical Methods of Material Testing P Czech Ostrava 2 Compulsory study plan
2006/2007 (N3909) Process Engineering (3911T008) Chemical and Physical Methods of Material Testing P Czech Ostrava 2 Compulsory study plan
2005/2006 (N3909) Process Engineering (3911T008) Chemical and Physical Methods of Material Testing P Czech Ostrava 2 Compulsory study plan

Occurrence in special blocks

Block nameAcademic yearForm of studyStudy language YearWSType of blockBlock owner