617-0411/01 – Solid Phase Structure (SPF)

Gurantor departmentDepartment of ChemistryCredits4
Subject guarantorprof. Ing. Boleslav Taraba, CSc.Subject version guarantorprof. Ing. Boleslav Taraba, CSc.
Study levelundergraduate or graduateRequirementCompulsory
Year3Semesterwinter
Study languageCzech
Year of introduction2004/2005Year of cancellation2011/2012
Intended for the facultiesFMTIntended for study typesBachelor
Instruction secured by
LoginNameTuitorTeacher giving lectures
TAR01 prof. Ing. Boleslav Taraba, CSc.
Extent of instruction for forms of study
Form of studyWay of compl.Extent
Full-time Credit and Examination 2+1

Subject aims expressed by acquired skills and competences

Learn the basic concepts: structural and textural properties of solids. Apply the knowledge gained to evaluate and quantify the solids. Aware of and seek mutual relations between the structural and textural characteristics and some physical properties of solids.

Teaching methods

Lectures
Experimental work in labs

Summary

Students will be acquainted with basic experimental approaches to study structural and physical parameters of the solids. Attention will be paid to infra red, nuclear magnetic and mass spectroscopies. Also, theories of monolayer (Langmuir) and multilayer (BET) adsorption, capillary condensation (Kelvin´ equation) as well as theory of micropores volume filling (Dubinin-Polanyi equation) will be studied.

Compulsory literature:

1) Silverstein,R.M., Bassler,G.C., Morril,T.C.: Spectrometric Identification of Organic Compounds. 5th edition, J.Wiley & Sons, New York 1991 2) George,W.O., McIntyre,P.S.: Infrared Spectroscopy - Analytical Chemistry by Open Learning, John Wiley & Sons, New York, 1990 3) Kalous,V.: Jak moderní chemie zkoumá strukturu molekul, SNTL, Praha, 1987 4) J.Zýka a kol.: Nové směry v analytické chemii, Sv 4, SNTL Praha, 1988 5) Ponec,V., Knor,Z., Černý,S.: Adsorpce na tuhých látkách, Praha SNTL, 1968 6) Gregg,S.J., Sing,K.S.W.: Adsorption, Surface Area and Porosity (2nd edition), Academic Pess, London, 1982 7) Taraba,B.: Chemická struktura pevné fáze, Učební texty OU, PřF, Ostravská univerzita 1995. 8) R.Ch.Bansal, J.B.Donnet, F.Stoeckli: Active Carbon, Marcel Dekker Inc., New York, 1988. 9) M.A.Wright, K.R.Palmer: Research into Structural Carbons, SIU, Carbondale, 1994

Recommended literature:

Way of continuous check of knowledge in the course of semester

E-learning

Další požadavky na studenta

Prerequisities

Subject has no prerequisities.

Co-requisities

Subject has no co-requisities.

Subject syllabus:

1) The textural properties of solids. Basic parameters of texture, density solids, porosity 2) The theory of adsorption on solids, adsorption isotherm, Brunnauer classification 3) Experimental procedures for determining the textural parameters 4) Types of adsorption ISOTERM, the theory of monomolecular Langmuir adsorption isotherm 5) The theory of multilayer adsorption (BET) 6) Adsorption in micropores, Polanyi potential, Dubinin-Raduškevič isotherm, calculations 7) Adsorption in mesopores, capillary condensation, Kelvin equation 8) Adsorption in a flow-through arrangement 9) The adsorption of gas mixtures, sorption of the liquid medium 10) The assessment of substances in terms of texture fractal geometry 11) The flow of gases and liquids porous environment, viscous flow, Knudsen diffusion, specific permeability 12) Experimental methods, apparatus, evaluation, reproducibility

Conditions for subject completion

Full-time form (validity from: 2011/2012 Winter semester, validity until: 2011/2012 Summer semester)
Task nameType of taskMax. number of points
(act. for subtasks)
Min. number of points
Exercises evaluation and Examination Credit and Examination 100 (100) 51
        Exercises evaluation Credit 30 (30) 16
                Written Written test 30  16
        Examination Examination 70 (70) 35
                Oral Oral examination 70  35
Mandatory attendence parzicipation:

Show history

Occurrence in study plans

Academic yearProgrammeField of studySpec.FormStudy language Tut. centreYearWSType of duty
2011/2012 (B3909) Process Engineering (2811R002) Fuel Chemistry and Technology P Czech Ostrava 3 Compulsory study plan
2010/2011 (B3909) Process Engineering (2811R002) Fuel Chemistry and Technology P Czech Ostrava 3 Compulsory study plan
2009/2010 (B3909) Process Engineering (2811R002) Fuel Chemistry and Technology P Czech Ostrava 3 Compulsory study plan
2008/2009 (B3909) Process Engineering (2811R002) Fuel Chemistry and Technology P Czech Ostrava 3 Compulsory study plan
2007/2008 (B3909) Process Engineering (2811R002) Fuel Chemistry and Technology P Czech Ostrava 3 Compulsory study plan
2006/2007 (B3909) Process Engineering (2811R002) Fuel Chemistry and Technology P Czech Ostrava 3 Compulsory study plan
2005/2006 (B3909) Process Engineering (2811R002) Fuel Chemistry and Technology P Czech Ostrava 3 Compulsory study plan

Occurrence in special blocks

Block nameAcademic yearForm of studyStudy language YearWSType of blockBlock owner