617-0411/02 – Solid Phase Structure (SPF)
| Gurantor department | Department of Chemistry | Credits | 5 |
| Subject guarantor | prof. Ing. Boleslav Taraba, CSc. | Subject version guarantor | prof. Ing. Boleslav Taraba, CSc. |
| Study level | undergraduate or graduate | Requirement | Compulsory |
| Year | 3 | Semester | winter |
| | Study language | Czech |
| Year of introduction | 2012/2013 | Year of cancellation | 2016/2017 |
| Intended for the faculties | FMT | Intended for study types | Bachelor |
Subject aims expressed by acquired skills and competences
Learn the basic concepts: structural and textural properties of solids. Apply the knowledge gained to evaluate and quantify the solids.
Aware of and seek mutual relations between the structural and textural characteristics and some physical properties of solids.
Teaching methods
Lectures
Experimental work in labs
Summary
Students will be acquainted with basic experimental approaches to study structural and physical parameters of the solids. Attention will be paid to infra red, nuclear magnetic and mass spectroscopies. Also, theories of monolayer (Langmuir) and multilayer (BET) adsorption, capillary condensation (Kelvin´ equation) as well as theory of micropores volume filling (Dubinin-Polanyi equation) will be studied.
Compulsory literature:
1) Silverstein,R.M., Bassler,G.C., Morril,T.C.: Spectrometric Identification of Organic Compounds. 5th edition, J.Wiley & Sons, New York 1991
2) George,W.O., McIntyre,P.S.: Infrared Spectroscopy - Analytical Chemistry by Open Learning, John Wiley & Sons, New York, 1990
3) Kalous,V.: Jak moderní chemie zkoumá strukturu molekul, SNTL, Praha, 1987
4) J.Zýka a kol.: Nové směry v analytické chemii, Sv 4, SNTL Praha, 1988
5) Ponec,V., Knor,Z., Černý,S.: Adsorpce na tuhých látkách, Praha SNTL, 1968
6) Gregg,S.J., Sing,K.S.W.: Adsorption, Surface Area and Porosity (2nd edition), Academic Pess, London, 1982
7) Taraba,B.: Chemická struktura pevné fáze, Učební texty OU, PřF, Ostravská univerzita 1995.
8) R.Ch.Bansal, J.B.Donnet, F.Stoeckli: Active Carbon, Marcel Dekker Inc., New York, 1988.
9) M.A.Wright, K.R.Palmer: Research into Structural Carbons, SIU, Carbondale, 1994
Recommended literature:
Additional study materials
Way of continuous check of knowledge in the course of semester
E-learning
Other requirements
Basic the knowledge of inorganic, organic and physical chemistry.
Prerequisities
Subject has no prerequisities.
Co-requisities
Subject has no co-requisities.
Subject syllabus:
1) The textural properties of solids. Basic parameters of texture, density
solids, porosity
2) The theory of adsorption on solids, adsorption isotherm, Brunnauer
classification
3) Experimental procedures for determining the textural parameters
4) Types of adsorption ISOTERM, the theory of monomolecular Langmuir adsorption isotherm
5) The theory of multilayer adsorption (BET)
6) Adsorption in micropores, Polanyi potential, Dubinin-Raduškevič isotherm, calculations
7) Adsorption in mesopores, capillary condensation, Kelvin equation
8) Adsorption in a flow-through arrangement
9) The adsorption of gas mixtures, sorption of the liquid medium
10) The assessment of substances in terms of texture fractal geometry
11) The flow of gases and liquids porous environment, viscous flow, Knudsen diffusion, specific permeability
12) Experimental methods, apparatus, evaluation, reproducibility
Conditions for subject completion
Occurrence in study plans
Occurrence in special blocks
Assessment of instruction