617-0810/01 – Organic Chemistry (OCH)
| Gurantor department | Department of Chemistry | Credits | 5 |
| Subject guarantor | doc. Ing. Petr Pánek, CSc. | Subject version guarantor | doc. Ing. Petr Pánek, CSc. |
| Study level | undergraduate or graduate | Requirement | Compulsory |
| Year | 1 | Semester | winter |
| | Study language | Czech |
| Year of introduction | 2005/2006 | Year of cancellation | 2015/2016 |
| Intended for the faculties | FMT | Intended for study types | Follow-up Master |
Subject aims expressed by acquired skills and competences
Repeticion of theoretical principles of the organic chemistry and extension of the knowledge about the most important groups of organic substances from the technical and biological point of view.
Teaching methods
Lectures
Tutorials
Experimental work in labs
Summary
The review of the key principles of the organic chemistry, modern methods of organic synthesis and organic analysis, as well as extension of the knowledge about the most important groups of organic compounds.
Compulsory literature:
Recommended literature:
Way of continuous check of knowledge in the course of semester
E-learning
Other requirements
There are no additional requirements for students.
Prerequisities
Subject has no prerequisities.
Co-requisities
Subject has no co-requisities.
Subject syllabus:
1. Lecture:
Introduction into the organic chemistry. History of organic chemistry. Bonding power of carbon (molecular orbitals, and bond, energy of bond, polarity of bond, hybridization, effects of electron). Relation between the structure and the properties of substances. Intermolecular interaction (Van der Waals interaction, interaction of dipole, hydrogen bridges) and their influence on the temperature of the reversion (thaw point, boiling point) and solubility.
Theoretical tutorial:
Bonding power of carbon.
2. Lecture:
Principles of stereochemistry of organic compounds. Drawing organic molecules (types of formulas, projection, models, 3D-shape of molecules). Polymerism and isomerism (constitution, geometric, enantiomerism). The conformation of organic compounds.
Theoretical tutorial:
Structure, formula, model. Inference of molecular formula, rational formula and structural formula. Determination of isomerism type by the concrete compounds.
3. Lecture:
Chemical reactions of organic compounds. Ranking of organic reactions. Homolysis and heterolysis. Electrophilic and nucleophilic agents. Aliphatic and alicyclic hydrocarbons. Nomenclature of saturated hydrocarbons. Radical substitution. Cracking (catalyzed and uncatalyzed) and isomerization. Fischer-Tropsch synthesis. Resources of hydrocarbons and their application.
Theoretical tutorial:
Nomenclature of organic compounds.
4. Lecture:
Unsaturated hydrocarbons. Radical and ion addition to double bond. Elimination reactions. Resources of unsaturated hydrocarbons and their industrial application.
Theoretical tutorial:
Nomenclature of organic compounds.
5. Lecture:
Aromatic compounds. Delocalization of electrons. Electrophilic aromatic substitution (nitration, sulfonation, alcylation, acylation, halogenation) and others reactions. Resources of aromates and their industrial application. Toxicity of polyaromatic compounds.
Theoretical tutorial:
Nomenclature of organic compounds.
6. Lecture:
Derivatives of hydrocarbons. Derivatives of halogens. Physical properties, toxicity and application. Synthesis and important reactions.
Theoretical tutorial:
Nomenclature of organic compounds.
7. Lecture:
Derivatives of nitrogen (nitrocompounds, amines, diazonium salts, azocompounds). Physical properties, toxicity and application. Synthesis and important reactions.
Practical tutorial:
Preparing of jodoform.
8. Lecture:
Derivatives of sulfure (thioalcohols and thiophenols, sulphides, sulfonic acids). Physical properties and application. Synthesis and important reactions. Detergents.
Practical tutorial:
Preparing of 4-nitroaniline.
9. Lecture:
Derivatives of oxygen. Alcohols and phenols. Ethers. Physical properties, toxicity and application. Synthesis and important reactions.
Practical tutorial:
Preparing of fumaric acid.
10. Lecture:
Carbonyl compounds (aldehydes and ketones). Physical properties, toxicity and application. Synthesis and important reactions. Organometallics. Reactivity, toxicity and application. Grignard reagents and their reactions.
Practical tutorial:
Preparing of acetylsalicyclic acid.
11. Lecture:
Carboxylic acids. Physical properties and application. Synthesis and important reactions (acidity versus structure, neutralization, esterification, decarboxylation).
Practical tutorial:
Preparing of ethyl formate.
12. Lecture:
Carboxylic acids derivatives. Halogenkyseliny. Hydroxykyseliny. Oxo carboxylic acids. Amino-acids. Physical properties and application. Synthesis and important reactions.
Practical tutorial:
Preparing of soda soap.
13. Lecture:
Functional derivatives of carboxylic acids. Acyl halides. Anhydrides. Esters. Amides. Nitriles. Physical properties, toxicity and application. Synthesis and important reactions.
Derivatives of carbonic acid (phosgene, urea and their sulfure analogues).
Theoretical tutorial: More important reactions of hydrocarbons and derivatives of hydrocarbons.
14. Lecture:
Polymers (divided, structure, properties, basic reactions of polymers preparing, summary of more important technical polymers).
Theoretical tutorial: Presentation of seminar papers.
Conditions for subject completion
Occurrence in study plans
Occurrence in special blocks
Assessment of instruction
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