617-1020/03 – Intercalated nanomaterials (IN)
Gurantor department | Department of Chemistry | Credits | 3 |
Subject guarantor | prof. Ing. Zdeněk Klika, CSc. | Subject version guarantor | prof. Ing. Zdeněk Klika, CSc. |
Study level | undergraduate or graduate | Requirement | Optional |
Year | 1 | Semester | summer |
| | Study language | Czech |
Year of introduction | 2016/2017 | Year of cancellation | 2020/2021 |
Intended for the faculties | USP | Intended for study types | Follow-up Master |
Subject aims expressed by acquired skills and competences
The student will be acquainted with methods used for the structure and texture study of the intercalated materials and will be able to apply them on the base level. He will be acquainted with composition, structure and properties of the basic intercalated materials, both phylosilicates and other host matrixes.
Teaching methods
Lectures
Individual consultations
Project work
Summary
Lectures continue the previous study of chemistry, physics of solids and layered silicates. In introduction lectures the student is acquainted with texture, catalytic properties of intercalated materials, ion-exchanged reactions and theory of guest bindings in host structures. The base of intercalation chemistry follows. It deals with various intercalation materials, host lattices, intercalation reactions, properties of ion-intercalation compounds, types of guests and methods used for the intercalation. Next lectures are focussed on: organo-clay complexes, sorption on nitro aromatic clay intercalates, photoprocess in clay-organic compounds, pillared and pore clay heterostructures and layered double hydroxides.
Compulsory literature:
[1] Auerbach, S.M. , Carrado, K.A.. Handbook of layered materials. New York, Marcel Dekker, Inc., 2004, 646 pp.
[2] LERF, A.: Intercalation compounds in layered host lattices: supramolecular
chemistry in nanodimensions (166 pp.) in: Hari Singh Nalwa (editor): Handbook
of Nanostructured Materials and Nanotechnology, vol. 5, Academic Press, San
Diego, 2000;
Recommended literature:
[1] WHITTINGHAM, M. S. and JACOBSON, A. J.: Intercalation Chemistry, Academic
Press, 1982.
Way of continuous check of knowledge in the course of semester
Check during the lectures.
E-learning
Not available.
Other requirements
Presentation of given issue by talk (handover of printed and pdf-documentation).
Prerequisities
Subject has no prerequisities.
Co-requisities
Subject has no co-requisities.
Subject syllabus:
In introduction lectures the student is acquainted with texture, catalytic properties of intercalated materials, ion-exchanged reactions and theory of guest bindings in host structures. The base of intercalation chemistry follows. It deals with various intercalation materials, host lattices, intercalation reactions, properties of ion-intercalation compounds, types of guests and methods used for the intercalation. Next lectures are focussed on: organo-clay complexes, sorption on nitro aromatic clay intercalates, photoprocess in clay-organic compounds, pillared and pore clay heterostructures and layered double hydroxides.
Conditions for subject completion
Occurrence in study plans
Occurrence in special blocks
Assessment of instruction