617-3025/01 – Intercalated nanomaterials (IN)

Gurantor departmentDepartment of ChemistryCredits2
Subject guarantordoc. Ing. Vlastimil Matějka, Ph.D.Subject version guarantordoc. Ing. Vlastimil Matějka, Ph.D.
Study levelundergraduate or graduateRequirementChoice-compulsory type A
Year1Semestersummer
Study languageCzech
Year of introduction2019/2020Year of cancellation
Intended for the facultiesFMTIntended for study typesFollow-up Master
Instruction secured by
LoginNameTuitorTeacher giving lectures
MAT27 doc. Ing. Vlastimil Matějka, Ph.D.
Extent of instruction for forms of study
Form of studyWay of compl.Extent
Full-time Examination 2+0

Subject aims expressed by acquired skills and competences

The aim of the subject is to provide the information about the intercalated materials, their properties and utilization. Student will understand: i) the issues related to the intercalation chemistry, ii) the methods used for the characterization of the products of the intercalation reactions, iii) intercalation of layered silicates and iv) pillared materials. Based on the knowledge obtained within the lectures the student is able to evaluate the application potential of intercalated and pillared materials.

Teaching methods

Lectures

Summary

The subject relates to the students knowledge in the field of chemistry, physics and chemistry of solid phase and layered materials. At the beginning the lectures are focused on the explanation of the terms layered materials, intercalation and subdivision of the intercalated materials. Next part concerns with the intercalation chemistry with attention to the properties of the intercalated materials their host lattices, itercalation reactions and the methods used for the intercalation. Following lectures deal with the methods used for the study of the structure, texture and optical properties of the intercalated materials. The topics related to cation exchange phenomenon in the layered phylosilicates, organo-clay complexes, preparation and the properties of clay/(conductive polymer) composites preparation and the properties of photofuncionalized intercalated clay materials are expressed during next lectures. The introduction to pillared and porous clay heterostructures and the overview of the application potential of intercalated and pillared materials are studied in the last part of the lectures.

Compulsory literature:

BERGAYA Faiza, Benny K. G. THENG a Gerhard LAGALY, ed. Handbook of clay science. Oxford: Elsevier, 2006. ISBN 0-08-044183-1. GIL, Antonio, S. A. KORILI, Raquel TRUJILLANO a Miguel Angel VICENTE, ed. Pillared clays and related catalysts. New York: Springer, 2010. ISBN 978-1-4419-6669-8. WHITTINGHAM, M. Stanley a Allan J. JACOBSON. Intercalation chemistry. New York: Academic Press, 1982. Materials science and technology (New York, N.Y.). ISBN 978-0-12-747380-2.

Recommended literature:

AUERBACH, Scott M., Kathleen A. CARRADO a Prabir K. DUTTA, ed. Handbook of layered materials. New York: Marcel Dekker, c2004. ISBN 0-8247-5349-6.

Way of continuous check of knowledge in the course of semester

Oral exam.

E-learning

Další požadavky na studenta

Elaboration of project on given topic.

Prerequisities

Subject has no prerequisities.

Co-requisities

Subject has no co-requisities.

Subject syllabus:

1. Layered materials, intercalation, types of the intercalated materials 2. Properties of the intercalated materials, host lattices, intercalation reactions, methods used for the intercalation. 3. The methods used for the study of the structure of the intercalated materials. 4. The methods used for the study of the texture of the intercalated materials. 5. The methods for the study of the optical properties of the intercalated materials. 6. Cation exchange capacity of clay minerals. 7. Intercalation of clay minerals, organo-clay complexes. 8. Preparation and properties of clay/polymer composites. 9. Preparation and the properties of clay/(conductive polymer) composites 10. Preparation and the properties of photofunctionable intercalated clay minerals. 11. Pillared and porous clay heterostructures. 12. Other types of the intercalated materials. 13. The examples of the practical utilization of the intercalated materials. 14. Presentation of the students’ projects.

Conditions for subject completion

Full-time form (validity from: 2019/2020 Summer semester)
Task nameType of taskMax. number of points
(act. for subtasks)
Min. number of points
Examination Examination 100  51
Mandatory attendence parzicipation: Elaboration of the seminary work on given topic.

Show history

Occurrence in study plans

Academic yearProgrammeField of studySpec.ZaměřeníFormStudy language Tut. centreYearWSType of duty
2020/2021 (N0719A270002) Nanotechnology CH2 P Czech Ostrava 1 Choice-compulsory type A study plan
2019/2020 (N0719A270002) Nanotechnology CH2 P Czech Ostrava 1 Choice-compulsory type A study plan

Occurrence in special blocks

Block nameAcademic yearForm of studyStudy language YearWSType of blockBlock owner