619-0025/01 – Special Topics in Physical Chemistry for Electrical Engineers (fche)

Gurantor departmentDepartment of Physical Chemistry and Theory of Technological ProcessesCredits8
Subject guarantorprof. Ing. Jana Dobrovská, CSc.Subject version guarantorprof. Ing. Jana Dobrovská, CSc.
Study levelundergraduate or graduateRequirementChoice-compulsory
Year3Semestersummer
Study languageCzech
Year of introduction2000/2001Year of cancellation2007/2008
Intended for the facultiesFEIIntended for study typesMaster
Instruction secured by
LoginNameTuitorTeacher giving lectures
DOB30 prof. Ing. Jana Dobrovská, CSc.
Extent of instruction for forms of study
Form of studyWay of compl.Extent
Full-time Credit and Examination 3+2

Subject aims expressed by acquired skills and competences

- to define the thermodynamic quantities and laws of thermodynamics - to describe the chemical equilibrium – to monitor the dependence of the equilibrium constant on state variables (dependence on temperature, dependence on pressure) - to describe the phase equilibrium - Gibbs phase rule, phase equilibria of pure substances and binary liquid systems - to define and utilize basic terms of chemical kinetics - rate of chemical reaction, kinetic equation, order of reaction, rate constant - to describe basic processes of heterogeneous reactions – diffusion, adsorption; to determine the rate-limiting process for heterogeneous processes - to apply gained theoretical knowledge in the field of material preparation in electrical engineering.

Teaching methods

Lectures
Individual consultations
Tutorials

Summary

The subject is focused on application of the laws and principles of Physical Chemistry in the field of material preparation in electrical engineering.

Compulsory literature:

Atkins,P.W., Physical Chemistry. Fourth Edition, Oxford: Oxford University Press, 1993. 995 p. Lupis,C.H.P.Chemical Thermodynamics of materials. New York, North-Holland, 1983. 581 p.Atkins,P.W., Physical Chemistry. Fourth Edition, Oxford: Oxford University Press, 1993. 995 p.

Recommended literature:

Way of continuous check of knowledge in the course of semester

E-learning

Další požadavky na studenta

Prerequisities

Subject has no prerequisities.

Co-requisities

Subject has no co-requisities.

Subject syllabus:

Signification of physical chemistry in electrotechnics and electronics. Thermodynamic state function for gases. Fugacity. Real gases. Heat capacities of substances, variation of heat capacities with temperature. Thermodynamic laws, theoretical calculation of reaction heat (enthalpy), variation of reaction enthalpy with temperature. Thermodynamic potentials, Gibbs-Helmholtz equations, chemical potential. Chemical equilibria: homogeneous, heterogeneous, equilibrium constants. Calculation of equilibrium composition. Phase equilibria, Gibbs phase rule, classification of systems. Thermodynamic of liquid solutions, Raoult’s law and Henry’s law. Real solutions, activity and activity coefficient. . Thermodynamic functions and models of solutions. Vaporization and distillation. Application of solutions theory on metal alloys. Structure and properties of liquid metals, melting, vaporization, surface tension, viscosity. Crystallisation. Homogeneous and heterogeneous nucleation. Distribution coefficients. Segregation process, crystallization, process modelling. Chemical kinetics: rate of chemical reaction, order of reaction, molecularity and reaction mechanism. Theory of chemical kinetics. Elementary steps in heterogenous reactions. Diffusion mechanism and mathematical description, molecular, molecular, convection and turbulent diffusion. Diffusion and chemical reaction, diffusion limited reactions, external and internal diffusion, diffusion through phase interface. Surface phenomena and kinetics of reactions. Surface properties of solid components. Physical adsorption and chemisorption. Adsorption isotherms. Gas adsorption kinetics. Surface properties of solutions, application of surface phenomena. Kinetics of topochemical reactions. Autocatalytic reactions. Industry application of heterogeneous kinetics.

Conditions for subject completion

Full-time form (validity from: 1960/1961 Summer semester)
Task nameType of taskMax. number of points
(act. for subtasks)
Min. number of points
Exercises evaluation and Examination Credit and Examination 100 (100) 51
        Exercises evaluation Credit 32 (32) 0
                Written exam Written test 30  0
                Other task type Other task type 2  0
        Examination Examination 68 (68) 0
                Written examination Written examination 18  0
                Oral Oral examination 50  0
Mandatory attendence parzicipation:

Show history

Occurrence in study plans

Academic yearProgrammeField of studySpec.FormStudy language Tut. centreYearWSType of duty
2007/2008 (M2612) Electrical Engineering and Computer Science (2612T018) Electronics and Communication Technology P Czech Ostrava 3 Choice-compulsory study plan
2006/2007 (M2612) Electrical Engineering and Computer Science (2612T018) Electronics and Communication Technology P Czech Ostrava 3 Choice-compulsory study plan
2006/2007 (M2612) Electrical Engineering and Computer Science (2601T004) Measurement and Control Engineering P Czech Ostrava Choice-compulsory study plan
2006/2007 (M2612) Electrical Engineering and Computer Science (2612T018) Electronics and Communication Technology P Czech Ostrava Choice-compulsory study plan
2006/2007 (M2612) Electrical Engineering and Computer Science (2642T004) Electrical Machines, Apparatus and Drives (10) Elektrické stroje a přístroje P Czech Ostrava Choice-compulsory study plan
2006/2007 (M2612) Electrical Engineering and Computer Science (2642T004) Electrical Machines, Apparatus and Drives (20) Elektrické pohony a výkonová elektronika P Czech Ostrava Choice-compulsory study plan
2006/2007 (M2612) Electrical Engineering and Computer Science (3902T023) Computer Science P Czech Ostrava Choice-compulsory study plan
2006/2007 (M2612) Electrical Engineering and Computer Science (3907T001) Electrical Power Engineering P Czech Ostrava Choice-compulsory study plan
2005/2006 (M2612) Electrical Engineering and Computer Science (2612T018) Electronics and Communication Technology P Czech Ostrava 3 Choice-compulsory study plan
2005/2006 (M2612) Electrical Engineering and Computer Science (2601T004) Measurement and Control Engineering P Czech Ostrava Choice-compulsory study plan
2005/2006 (M2612) Electrical Engineering and Computer Science (2612T018) Electronics and Communication Technology P Czech Ostrava Choice-compulsory study plan
2005/2006 (M2612) Electrical Engineering and Computer Science (2642T004) Electrical Machines, Apparatus and Drives (10) Elektrické stroje a přístroje P Czech Ostrava Choice-compulsory study plan
2005/2006 (M2612) Electrical Engineering and Computer Science (2642T004) Electrical Machines, Apparatus and Drives (20) Elektrické pohony a výkonová elektronika P Czech Ostrava Choice-compulsory study plan
2005/2006 (M2612) Electrical Engineering and Computer Science (3902T023) Computer Science P Czech Ostrava Choice-compulsory study plan
2005/2006 (M2612) Electrical Engineering and Computer Science (3907T001) Electrical Power Engineering P Czech Ostrava Choice-compulsory study plan
2004/2005 (M2612) Electrical Engineering and Computer Science (2612T018) Electronics and Communication Technology P Czech Ostrava 3 Choice-compulsory study plan
2004/2005 (M2612) Electrical Engineering and Computer Science (2601T004) Measurement and Control Engineering P Czech Ostrava Choice-compulsory study plan
2004/2005 (M2612) Electrical Engineering and Computer Science (2612T018) Electronics and Communication Technology P Czech Ostrava Choice-compulsory study plan
2004/2005 (M2612) Electrical Engineering and Computer Science (2642T004) Electrical Machines, Apparatus and Drives (10) Elektrické stroje a přístroje P Czech Ostrava Choice-compulsory study plan
2004/2005 (M2612) Electrical Engineering and Computer Science (2642T004) Electrical Machines, Apparatus and Drives (20) Elektrické pohony a výkonová elektronika P Czech Ostrava Choice-compulsory study plan
2004/2005 (M2612) Electrical Engineering and Computer Science (3902T023) Computer Science P Czech Ostrava Choice-compulsory study plan
2004/2005 (M2612) Electrical Engineering and Computer Science (3907T001) Electrical Power Engineering P Czech Ostrava Choice-compulsory study plan
2003/2004 (M2612) Electrical Engineering and Computer Science (2612T018) Electronics and Communication Technology P Czech Ostrava 3 Choice-compulsory study plan
2003/2004 (M2612) Electrical Engineering and Computer Science (2601T004) Measurement and Control Engineering P Czech Ostrava Choice-compulsory study plan
2003/2004 (M2612) Electrical Engineering and Computer Science (2612T018) Electronics and Communication Technology P Czech Ostrava Choice-compulsory study plan
2003/2004 (M2612) Electrical Engineering and Computer Science (2642T004) Electrical Machines, Apparatus and Drives (10) Elektrické stroje a přístroje P Czech Ostrava Choice-compulsory study plan
2003/2004 (M2612) Electrical Engineering and Computer Science (2642T004) Electrical Machines, Apparatus and Drives (20) Elektrické pohony a výkonová elektronika P Czech Ostrava Choice-compulsory study plan
2003/2004 (M2612) Electrical Engineering and Computer Science (3902T023) Computer Science P Czech Ostrava Choice-compulsory study plan
2003/2004 (M2612) Electrical Engineering and Computer Science (3907T001) Electrical Power Engineering P Czech Ostrava Choice-compulsory study plan
2002/2003 (M2612) Electrical Engineering and Computer Science (2612T018) Electronics and Communication Technology P Czech Ostrava 3 Choice-compulsory study plan
2002/2003 (M2612) Electrical Engineering and Computer Science (2601T004) Measurement and Control Engineering P Czech Ostrava Choice-compulsory study plan
2002/2003 (M2612) Electrical Engineering and Computer Science (2612T018) Electronics and Communication Technology P Czech Ostrava Choice-compulsory study plan
2002/2003 (M2612) Electrical Engineering and Computer Science (2642T004) Electrical Machines, Apparatus and Drives (10) Elektrické stroje a přístroje P Czech Ostrava Choice-compulsory study plan
2002/2003 (M2612) Electrical Engineering and Computer Science (2642T004) Electrical Machines, Apparatus and Drives (20) Elektrické pohony a výkonová elektronika P Czech Ostrava Choice-compulsory study plan
2002/2003 (M2612) Electrical Engineering and Computer Science (3902T023) Computer Science P Czech Ostrava Choice-compulsory study plan
2002/2003 (M2612) Electrical Engineering and Computer Science (3907T001) Electrical Power Engineering P Czech Ostrava Choice-compulsory study plan
2001/2002 (M2612) Electrical Engineering and Computer Science (2612T018) Electronics and Communication Technology P Czech Ostrava 3 Choice-compulsory study plan

Occurrence in special blocks

Block nameAcademic yearForm of studyStudy language YearWSType of blockBlock owner