619-0404/01 – Theoretical Fundamentals of Technological Processes (TZTCH)
| Gurantor department | Department of Physical Chemistry and Theory of Technological Processes | Credits | 3 |
| Subject guarantor | prof. Ing. Jana Dobrovská, CSc. | Subject version guarantor | prof. Ing. Jana Dobrovská, CSc. |
| Study level | undergraduate or graduate | Requirement | Compulsory |
| Year | 2 | Semester | winter |
| | Study language | Czech |
| Year of introduction | 2007/2008 | Year of cancellation | 2014/2015 |
| Intended for the faculties | FMT | Intended for study types | Bachelor |
Subject aims expressed by acquired skills and competences
- to define thermodynamic quantities, thermodynamic laws and fundamental principles of chemical and
phase equilibrium
- to use the chemical kinetics basic terms and relations
- to apply basic thermodynamic and kinetics terms and relations on technological
processes
- to outline some of the more important properties of liquid metal melts and slags
- to apply gained theoretical knowledge in routine
Teaching methods
Lectures
Individual consultations
Tutorials
Summary
The topic of the subject is theoretical foundation in the area of application
of the physical chemistry principles to particular technological processes.
Compulsory literature:
[1] ATKINS,Peter; De Paula,Julio. Elements of Physical chemistry. Fifth Edition. Oxford: University of Oxford, 2009. 578s.
Recommended literature:
[1] MOORE, John Jeremy. Chemical Metallurgy . 2nd ed. Oxford : Butterworth-Heinemann, 1990. 435 s.
Way of continuous check of knowledge in the course of semester
- one calculation exam
- active participation in seminars
E-learning
Other requirements
No other activities required.
Prerequisities
Subject has no prerequisities.
Co-requisities
Subject has no co-requisities.
Subject syllabus:
Physical chemistry, its significance in technological processes. Chemical thermodynamics - heat capacities, definition, classification. The First law of thermodynamics, analysis, application. Enthalpy, heating and coolling of substances, reaction enthalpy. The Second law of thermodynamics – some application for chemical and physical equilibriums. Equilibrium constants and their types for homogeneous nad heterogeneous chemical reactions.
Phase equilibrium. Gibbs phase rule. Phase equilibria in one-component two-phase systems.
Liquid solutions, properties, description of solutions, thermodynamic models of solutions.
Chemical kinetics – basic terms (rate of chemical reaction, molecularity, order of reaction, reaction mechanism). Kinetics of homogeneous simple reactions. Kinetics of heterogeneous chemical reactions, elementary steps in heterogenous reactions, diffusion, adsorption. Application in technological processes.
Liquid metals and liquid metal oxide systems, structure, physico-chemical properties (viscosity, surface tension, adsorption). Physical and metallurgical aspects of gases in molten metal, the Sievert's law. Liquid slags, structure, physico-chemical propeties. Slag-metal reactions.
Conditions for subject completion
Occurrence in study plans
Occurrence in special blocks
Assessment of instruction
Předmět neobsahuje žádné hodnocení.