619-0406/01 – Physical Chemistry II (FCHII)
| Gurantor department | Department of Physical Chemistry and Theory of Technological Processes | Credits | 9 |
| Subject guarantor | prof. Ing. Jana Dobrovská, CSc. | Subject version guarantor | prof. Ing. Ľudovít Dobrovský, CSc., dr. h. c. |
| Study level | undergraduate or graduate | Requirement | Compulsory |
| Year | 2 | Semester | summer |
| | Study language | Czech |
| Year of introduction | 2009/2010 | Year of cancellation | 2015/2016 |
| Intended for the faculties | HGF | Intended for study types | Bachelor |
Subject aims expressed by acquired skills and competences
- to define solutions - experience laws, thermodynamic quantities and models of
solutions
- to analyse phase diagrams of binary liquid mixtures
- to define and to utilize basic terms of chemical kinetics - homogeneous and
heterogeneous reaction, rate of chemical reaction, kinetic equation, order of
reaction, rate constant
- to monitor the dependence of the reaction rate on temperature
- to describe basic processes of heterogeneous reactions – diffusion, adsorption;
- to apply gained theoretical knowledge in routineto apply thermodynamic
quantities to electrolyte solutions
- to outline usage possibilities of electrochemical systems - electrodes,
electrolysis, galvanic cells
- to to describe properties of selected dispersion systems
- to apply gained theoretical knowledge in routine
Teaching methods
Lectures
Tutorials
Summary
Obsahem předmětu je chemická kinetika, elektrochemie a základy koloidní chemie.
Compulsory literature:
Atkins,P.W., Physical Chemistry. Fourth Edition, Oxford: Oxford University
Press, 1993. 995 p.
Lupis,C.H.P.Chemical Thermodynamics of materials. New York, North-Holland,
1983. 581 p.
Recommended literature:
Way of continuous check of knowledge in the course of semester
- two calculation exam
- active participation in seminars
E-learning
Other requirements
No other activities required.
Prerequisities
Co-requisities
Subject has no co-requisities.
Subject syllabus:
Chemical kinetics – classification of reactions, basic terms (reaction rate in homogeneous and heterogeneous systems, order of reaction, molecularity, rate constant, reaction mechanism). Integrated forms of the kinetic equation. The temperature dependence of the rate of a chemical reaction, Arrhenius equation. Kinetics of heterogeneous chemical reactions, elementary steps in heterogenous reactions.
Electrochemistry – electrolytes and theory of electrolytic dissociation. Strong electrolytes - activity and activitiy coefficient, Debye-Hückel limiting law. Solubility product. Equilibrium and dissociation in solutions of weak electrolytes - dissociation of week monobasic acids and bases, hydrolysis of salt, buffer solutions. Electrolysis, transport number, electric conductivity of electrolytes. Electrochemistry potentials, electrodes, galvanic cells.
Colloid chemistry - classification of dispersion systems, degree of dispersion. Selected kinetic, electrical and optical properties of colloid systems. Heterogeneous dispersion systems (lyophobic sols, emulsion, foam, aerosol).
Conditions for subject completion
Occurrence in study plans
Occurrence in special blocks
Assessment of instruction
Předmět neobsahuje žádné hodnocení.