619-0905/02 – Advanced Physical Chemistry (VKFCH)
| Gurantor department | Department of Physical Chemistry and Theory of Technological Processes | Credits | 10 |
| Subject guarantor | prof. Ing. Ľudovít Dobrovský, CSc., dr. h. c. | Subject version guarantor | prof. Ing. Ľudovít Dobrovský, CSc., dr. h. c. |
| Study level | postgraduate | Requirement | Choice-compulsory |
| Year | | Semester | winter + summer |
| | Study language | Czech |
| Year of introduction | 2011/2012 | Year of cancellation | |
| Intended for the faculties | FMT | Intended for study types | Doctoral |
Subject aims expressed by acquired skills and competences
- to apply the phase equilibria in multicomponent systems on selected processes in the chemical research and practice
- to apply the properties of multiphase systems in science and research
Teaching methods
Lectures
Individual consultations
Summary
Thermodynamics of solution – non-electrolyte solutions (empirical laws, ideal,
dilute and real solutions, partial molar quantities, thermodynamics functions
and models) colligative properties, phase diagrams - binary liquid miscible
and immiscible mixtures.
Physico-chemical properties of colloid systems, surfaces and multiphase systems, classification of dispersions; distribution function of particles size; optical, electrical and molecular-kinetic properties of
colloids; structure of colloid particles; physical chemistry of phases interfaces; molecular colloids.
Compulsory literature:
ATKINS,P.W. Physical Chemistry. Fourth Edition, Oxford: Oxford University
Press, 1993. 995 s.
Lupis,C.H.P. Chemical themodynamics of materials. North – Holland, New York 1983.
http://www.whfreeman.com/pchem7/index.htm
Recommended literature:
Lupis,C.H.P. Chemical themodynamics of materials. North – Holland, New York 1983.
Current articles in professional journals.
Way of continuous check of knowledge in the course of semester
Ústní zkouška s písemnou přípravou
E-learning
Other requirements
No other activities are required.
Prerequisities
Subject has no prerequisities.
Co-requisities
Subject has no co-requisities.
Subject syllabus:
Thermodynamic models of solutions. Colligative properties of solutions.
Properties of polycomponent liquids at different miscibility of the component. Phase diagrams and their technological applications.
Physical Chemistry of the phase interface, the phase interface effect on the thermodynamic properties of the system, surface and interfacial energy balance at the surface of contact of three phases, curved phase interface. Electrical properties of phase interfaces, electrical double layer, electrokinetic potential and electrokinetic phenomena.
Molecular-kinetic properties, thermal motion, sedimentation phenomena, membrane equilibrium. Optical and mechanical properties of systems.Stavové změny a význam disperzních soustav.
Physical chemistry of disperse systems and their classification.Phase dispersion systems, the stability of heterogeneous lyophobic systems, methods of preparation. Molecular colloids, solutions of high molecular weight electrolytes and nonelectrolytes, the behavior of macromolecules in solution, the selected properties and stability. Micellar colloids. Systems with continuous dispersion proportion gels.
Chapter selection will be made based on the orientation of the doctoral dissertation together with the supervisor.
Conditions for subject completion
Occurrence in study plans
Occurrence in special blocks
Assessment of instruction
Předmět neobsahuje žádné hodnocení.