619-2006/01 – Physical Chemistry (FCH)

Gurantor departmentDepartment of Physical Chemistry and Theory of Technological ProcessesCredits4
Subject guarantorprof. Ing. Kamila Kočí, Ph.D.Subject version guarantorprof. Ing. Kamila Kočí, Ph.D.
Study levelundergraduate or graduateRequirementChoice-compulsory
Year2Semesterwinter
Study languageCzech
Year of introduction2015/2016Year of cancellation
Intended for the facultiesFSIntended for study typesBachelor
Instruction secured by
LoginNameTuitorTeacher giving lectures
KOC33 prof. Ing. Kamila Kočí, Ph.D.
Extent of instruction for forms of study
Form of studyWay of compl.Extent
Part-time Graded credit 6+6

Subject aims expressed by acquired skills and competences

- count state behavior of gases at low pressures. - orient themselves in the use of basic thermodynamic functions. - count reaction heat balance and simple chemical reactions. - orient themselves in phase diagrams and solve vapor-liquid equilibrium for ideal behavior. - count kinetics of simple reactions

Teaching methods

Lectures
Individual consultations
Tutorials

Summary

The subject covers part of elementary physical chemistry (fundamental concepts and quantities, state behavior, fundamentals of thermodynamics), continued topics from the field of phase equilibria, chemical equilibria, selected topics from the field of the properties and behavior of systems containing electrolytes and description of the rate of chemical reactions.

Compulsory literature:

[1] ATKINS,Peter; De Paula,Julio. Elements of Physical chemistry. Fifth Edition. Oxford: University of Oxford, 2009. 578s.

Recommended literature:

[1] Atkins P.W., de Paula J., Physical Chemistry, Oxford University Press, 2010, 9780199543373

Way of continuous check of knowledge in the course of semester

Written test and oral interview.

E-learning

Other requirements

No other activities are required.

Prerequisities

Subject has no prerequisities.

Co-requisities

Subject has no co-requisities.

Subject syllabus:

Introduction. Gases. Ideal gases, fundamental laws. The chemical thermodynamics. Basic terms, thermodynamic system, thermodynamic properties, thermodynamic process, thermodynamic state functions. Heat capacities of substances. The First law of thermodynamics, definition, signification. The heating and cooling of substances. The heat of reaction, laws of thermochemistry, variation of the reaction enthalpy with temperature. Second law of thermodynamics – definition and signification. Helmholtz and Gibbs free energy. Conditions of thermodynamic equilibrium. Chemical equilibrium. Conditions for chemical equilibrium. The van´t Hoff reaction isotherm, thermodynamic equilibrium constant. Types of equilibrium constant for homogeneous and heterogeneous chemical reactions. The calculation of equilibrium composition and degree of conversion. The effect of temperature on chemical equilibrium.The effect of pressure on chemical equilibrium. The Le Chatelier’s principle. The phase equilibrium. The phase diagram of a one-component system, triple point and critical point. Phase equilibrium of pure substances, Clapeyron and Clausius Clapeyron equation. Phase equilibria in binary systems. Experience laws - Raoult´s and Henry´s laws. Phase diagrams of two-component liquid mixtures (isothermal diagram, isobaric diagram, y-x diagram, miscible liquids, partially miscible liquids, totally immiscible liquids). Distillation, simple distillation, rectification, azeotropic points, azeotropic mixtures, explaining the deviations. The chemical kinetics, significance. Homogeneous simple reactions. Basic terms, rate of chemical reaction, order of reaction, molecularity, rate constant, reaction mechanism. First-order reactions, reaction half-life, second-order reactions. The temperature dependence of the rate of a chemical reaction, Arrhenius equation. Kinetics of heterogeneous chemical reactions.

Conditions for subject completion

Part-time form (validity from: 2015/2016 Winter semester)
Task nameType of taskMax. number of points
(act. for subtasks)
Min. number of pointsMax. počet pokusů
Graded credit Graded credit 100  51 3
Mandatory attendence participation:

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Conditions for subject completion and attendance at the exercises within ISP:

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Occurrence in study plans

Academic yearProgrammeBranch/spec.Spec.ZaměřeníFormStudy language Tut. centreYearWSType of duty
2022/2023 (B3907) Energetics (3907R012) Energetics of the 21st Century K Czech Ostrava 2 Choice-compulsory study plan
2021/2022 (B3907) Energetics (3907R012) Energetics of the 21st Century K Czech Ostrava 2 Choice-compulsory study plan
2020/2021 (B3907) Energetics (3907R012) Energetics of the 21st Century K Czech Ostrava 2 Choice-compulsory study plan
2019/2020 (B3907) Energetics (3907R012) Energetics of the 21st Century K Czech Ostrava 2 Choice-compulsory study plan
2018/2019 (B3907) Energetics (3907R012) Energetics of the 21st Century K Czech Ostrava 2 Choice-compulsory study plan
2017/2018 (B3907) Energetics (3907R012) Energetics of the 21st Century K Czech Ostrava 2 Choice-compulsory study plan
2016/2017 (B3907) Energetics (3907R012) Energetics of the 21st Century K Czech Ostrava 2 Choice-compulsory study plan
2015/2016 (B3907) Energetics (3907R012) Energetics of the 21st Century K Czech Ostrava 2 Choice-compulsory study plan

Occurrence in special blocks

Block nameAcademic yearForm of studyStudy language YearWSType of blockBlock owner

Assessment of instruction

Předmět neobsahuje žádné hodnocení.