635-0940/01 – Thermodynamics of heterogeneous systems (THS)

Gurantor departmentDepartment of Thermal EngineeringCredits10
Subject guarantordoc. Ing. Jozef Vlček, Ph.D.Subject version guarantordoc. Ing. Václava Tomková, CSc.
Study levelpostgraduateRequirementChoice-compulsory
YearSemesterwinter + summer
Study languageCzech
Year of introduction2011/2012Year of cancellation
Intended for the facultiesFMTIntended for study typesDoctoral
Instruction secured by
LoginNameTuitorTeacher giving lectures
TOM32 doc. Ing. Václava Tomková, CSc.
VLC37 doc. Ing. Jozef Vlček, Ph.D.
Extent of instruction for forms of study
Form of studyWay of compl.Extent
Full-time Examination 2+0
Combined Examination 28+0

Subject aims expressed by acquired skills and competences

Extend students' knowledge in field thermodynamics homogenous systems. Solution of chemical equilibrium in heterogeneous systems. Identification and application phase equilibria in one and multicomponent systems.

Teaching methods

Individual consultations

Summary

Předmět definuje oboru termodynamiky heterogenních keramických systémů. Seznamuje studenty se zákonitostmi fázové stability keramických systémů, klade si za cíl osvojení pravidel interpretace vícelsožkových rovnovážných fázových diagramů. Pozornost je věnovaná schopnosti umět posuzovat korozní odolnost keramických systémů v místech jejich instalace.

Compulsory literature:

LEVIN, E. M. et al. Phase Diagrams for Ceramists. The Amer. Ceram. Soc., 1956-1991.

Recommended literature:

[1] MOORE, W. K. Fyzikální chemie (český překlad). Praha : SNTL, 1981. [2] ŠESTÁK, J. Měření termofyzikálních vlastností pevných látek. Praha : Academia, 1982.

Way of continuous check of knowledge in the course of semester

E-learning

Další požadavky na studenta

Prerequisities

Subject has no prerequisities.

Co-requisities

Subject has no co-requisities.

Subject syllabus:

The first law of thermodynamics, the standard state, enthalpy, heat of reaction. The heat capacity, heat of reaction dependence on temperature applications. The second law of thermodynamics, entropy, energy functions F and G, the conditions of thermodynamic equilibrium. 1-component systems, the balance in them, and enantiotropní monotropní transformation. Polymorphic transformation first and 2 order. The equilibrium constant of chemical reaction, its dependence on temperature. Alternative options determine the reaction enthalpy and Gibbs equilibrium constants. Applications for major types of reactions in heterogeneous systems. Thermodynamic analysis of 2 - and 3-component systems. Binary and ternary phase diagrams. Use of diagrams in the preparation of specific systems and applications of ceramic materials. Richardson-Jeffesův diagram, solution reduction of oxides, nitrogen mutual stability and behavior under different partial pressure of oxygen, applications.

Conditions for subject completion

Full-time form (validity from: 2013/2014 Winter semester)
Task nameType of taskMax. number of points
(act. for subtasks)
Min. number of points
Examination Examination  
Mandatory attendence parzicipation:

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Occurrence in study plans

Academic yearProgrammeField of studySpec.FormStudy language Tut. centreYearWSType of duty
2019/2020 (P2106) Metallurgy (2109V037) Thermal Engineering and Fuels in Industry P Czech Ostrava Choice-compulsory study plan
2019/2020 (P2106) Metallurgy (2109V037) Thermal Engineering and Fuels in Industry K Czech Ostrava Choice-compulsory study plan
2018/2019 (P2106) Metallurgy (2109V037) Thermal Engineering and Fuels in Industry P Czech Ostrava Choice-compulsory study plan
2018/2019 (P2106) Metallurgy (2109V037) Thermal Engineering and Fuels in Industry K Czech Ostrava Choice-compulsory study plan
2017/2018 (P2106) Metallurgy (2109V037) Thermal Engineering and Fuels in Industry P Czech Ostrava Choice-compulsory study plan
2017/2018 (P2106) Metallurgy (2109V037) Thermal Engineering and Fuels in Industry K Czech Ostrava Choice-compulsory study plan
2016/2017 (P2106) Metallurgy (2109V037) Thermal Engineering and Fuels in Industry P Czech Ostrava Choice-compulsory study plan
2016/2017 (P2106) Metallurgy (2109V037) Thermal Engineering and Fuels in Industry K Czech Ostrava Choice-compulsory study plan
2015/2016 (P2106) Metallurgy (2109V037) Thermal Engineering and Fuels in Industry P Czech Ostrava Choice-compulsory study plan
2015/2016 (P2106) Metallurgy (2109V037) Thermal Engineering and Fuels in Industry K Czech Ostrava Choice-compulsory study plan
2014/2015 (P2106) Metallurgy (2109V037) Thermal Engineering and Fuels in Industry P Czech Ostrava Choice-compulsory study plan
2014/2015 (P2106) Metallurgy (2109V037) Thermal Engineering and Fuels in Industry K Czech Ostrava Choice-compulsory study plan
2013/2014 (P2106) Metallurgy (2109V037) Thermal Engineering and Fuels in Industry P Czech Ostrava Choice-compulsory study plan
2013/2014 (P2106) Metallurgy (2109V037) Thermal Engineering and Fuels in Industry K Czech Ostrava Choice-compulsory study plan
2012/2013 (P2106) Metallurgy (2109V037) Thermal Engineering and Fuels in Industry P Czech Ostrava Choice-compulsory study plan
2012/2013 (P2106) Metallurgy (2109V037) Thermal Engineering and Fuels in Industry K Czech Ostrava Choice-compulsory study plan
2011/2012 (P2106) Metallurgy (2109V037) Thermal Engineering and Fuels in Industry P Czech Ostrava Choice-compulsory study plan
2011/2012 (P2106) Metallurgy (2109V037) Thermal Engineering and Fuels in Industry K Czech Ostrava Choice-compulsory study plan

Occurrence in special blocks

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