635-2008/01 – Thermodynamics of Ceramic systems (TeDKS)

Gurantor departmentDepartment of Thermal EngineeringCredits6
Subject guarantordoc. Ing. Jozef Vlček, Ph.D.Subject version guarantordoc. Ing. Jozef Vlček, Ph.D.
Study levelundergraduate or graduateRequirementCompulsory
Year3Semesterwinter
Study languageCzech
Year of introduction2014/2015Year of cancellation
Intended for the facultiesFMTIntended for study typesBachelor
Instruction secured by
LoginNameTuitorTeacher giving lectures
TOP36 Ing. Michaela Topinková, Ph.D.
VLC37 doc. Ing. Jozef Vlček, Ph.D.
Extent of instruction for forms of study
Form of studyWay of compl.Extent
Full-time Credit and Examination 2+3
Combined Credit and Examination 16+0

Subject aims expressed by acquired skills and competences

- student will be able to characterize the basic concepts and contexts of thermodynamics of homogenous states - student will be able to express the chemical balance in heterogeneous systems - student will be able to define and to apply the phase balance in single and multi-component systems - student will be able to apply the theoretical knowledge in assessing of thermal stability of ceramic systems - student will be able to assess the oxide stability

Teaching methods

Lectures
Tutorials

Summary

To give students the basic theoretical knowledge from the field of thermodynamics of ceramic materials. To acquaint students with essential thermodynamic laws applicable in ceramic systems. Special attention is devoted to interpretation of knowledge resulting from analyses of balanced phase diagrams.

Compulsory literature:

[1] BERRY, R. S., RICE. S. A., ROSS, J. Physical Chemistry. 2nd edition. New York: Oxford Univ. Press, 2000. ISBN 0-19-510589-3.

Recommended literature:

Articles in technical journals, papers of conferences, research reports, theses.

Way of continuous check of knowledge in the course of semester

E-learning

Další požadavky na studenta

There are no next requirements

Prerequisities

Subject has no prerequisities.

Co-requisities

Subject has no co-requisities.

Subject syllabus:

1. Introduction to thermodynamics. The first thermodynamic law, expression for defined process conditions. Enthalpy, reaction heat, standard states. 2. Calculation of reaction heat from enthalpy of formation. Calculation of reaction heat from combustion and dissolving enthalpy. 3. The thermal capacity of substances. Dependence of reaction heat on temperature. 4. The second thermodynamic law. Entropy. Linked formulation of 1. and 2. thermodynamic law. 5. Dependence of entropy on state variables. Change of entropy during the phase changes and chemical reactions. Energetic function F and G and their dependence on state variables. 6. Conditions of thermodynamic balance for specific systems. Partial molar quantities, Gibbs-Duhem equation. 7. Balance in one-component system, Clapeyron equal. Clausius-Clapeyron equal, application. 8. Enantiotropy and monotropy changes in one-component systems. Polymorphic modifications 1. and 2. order. 9. Equal constant of chemical reaction, its dependence on temperature. 10. Alternative possibility of determination of Gibbs reaction enthalpy and equal constant. Equal constant of destructive reaction AB(s)→A(s)+B(g), application. 11. Gibbs phase law, application. Thermodynamic analyse of two-component system, binary phase diagrams. 12. Rules of representation 3- and 4-component systems, ternary phase diagrams. 13. Richardson-Jeffs diagram, mutual stability of oxides. 14. Reduction of oxides by hydrogen and carbon oxide. Reduction of oxides by carbon. Stability of oxides with different partial pressure of oxygen.

Conditions for subject completion

Combined form (validity from: 2014/2015 Winter semester)
Task nameType of taskMax. number of points
(act. for subtasks)
Min. number of points
Exercises evaluation and Examination Credit and Examination 100 (100) 51
        Exercises evaluation Credit 30  15
        Examination Examination 70  36
Mandatory attendence parzicipation:

Show history

Occurrence in study plans

Academic yearProgrammeField of studySpec.FormStudy language Tut. centreYearWSType of duty
2019/2020 (B2109) Metallurgical Engineering (2109R039) Thermal Engineering and Ceramic Materials K Czech Ostrava 3 Compulsory study plan
2019/2020 (B2109) Metallurgical Engineering (2109R039) Thermal Engineering and Ceramic Materials P Czech Ostrava 3 Compulsory study plan
2018/2019 (B2109) Metallurgical Engineering (2109R039) Thermal Engineering and Ceramic Materials P Czech Ostrava 3 Compulsory study plan
2018/2019 (B2109) Metallurgical Engineering (2109R039) Thermal Engineering and Ceramic Materials K Czech Ostrava 3 Compulsory study plan
2017/2018 (B2109) Metallurgical Engineering (2109R039) Thermal Engineering and Ceramic Materials P Czech Ostrava 3 Compulsory study plan
2017/2018 (B2109) Metallurgical Engineering (2109R039) Thermal Engineering and Ceramic Materials K Czech Ostrava 3 Compulsory study plan
2016/2017 (B2109) Metallurgical Engineering (2109R039) Thermal Engineering and Ceramic Materials P Czech Ostrava 3 Compulsory study plan
2016/2017 (B2109) Metallurgical Engineering (2109R039) Thermal Engineering and Ceramic Materials K Czech Ostrava 3 Compulsory study plan
2015/2016 (B2109) Metallurgical Engineering (2109R039) Thermal Engineering and Ceramic Materials P Czech Ostrava 3 Compulsory study plan
2015/2016 (B2109) Metallurgical Engineering (2109R039) Thermal Engineering and Ceramic Materials K Czech Ostrava 3 Compulsory study plan
2014/2015 (B2109) Metallurgical Engineering (2109R039) Thermal Engineering and Ceramic Materials P Czech Ostrava 3 Compulsory study plan
2014/2015 (B2109) Metallurgical Engineering (2109R039) Thermal Engineering and Ceramic Materials K Czech Ostrava 3 Compulsory study plan

Occurrence in special blocks

Block nameAcademic yearForm of studyStudy language YearWSType of blockBlock owner