635-3035/01 – Thermodynamics of Ceramic systems (TKS)

Gurantor departmentDepartment of Thermal EngineeringCredits6
Subject guarantordoc. Ing. Hana Ovčačíková, Ph.D.Subject version guarantordoc. Ing. Hana Ovčačíková, Ph.D.
Study levelundergraduate or graduateRequirementCompulsory
Year1Semestersummer
Study languageCzech
Year of introduction2019/2020Year of cancellation
Intended for the facultiesFMTIntended for study typesFollow-up Master
Instruction secured by
LoginNameTuitorTeacher giving lectures
TOP36 Ing. Michaela Topinková, Ph.D.
VLC37 prof. Ing. Jozef Vlček, Ph.D.
Extent of instruction for forms of study
Form of studyWay of compl.Extent
Full-time Credit and Examination 2+3
Part-time Credit and Examination 16+0

Subject aims expressed by acquired skills and competences

Student will be able: - to characterize the basic concepts and contexts of thermodynamics of homogenous states - to express the chemical balance in heterogeneous systems - define and to apply the phase balance in single and multi-component systems - able to apply the theoretical knowledge in assessing of thermal stability of ceramic systems

Teaching methods

Lectures
Tutorials

Summary

The course contents are basic theoretical knowledge from the field of thermodynamics of ceramic materials. Students are familiar with the basic thermodynamic principles applicable in ceramic systems. Particular attention is paid to the interpretation of knowledge resulting from the analysis of equilibrium phase diagrams and the stability problems of the oxide systems.

Compulsory literature:

[1] BERRY, R. S., RICE. S. A., ROSS, J. Physical Chemistry. 2nd edition. New York: Oxford Univ. Press, 2000. ISBN 0-19-510589-3. [2] CARTER, C. B., NORTON, M. G. Ceramic Materials: Science and Engineering. 2nd ed. New York: Springer, 2013. ISBN 978-1-4614-3522-8. [3] CHINN, R., E. Ceramography: preparation and analysis of ceramic microstructures. ASM International, 2002. ISBN 978-0-87170-770-3. [4] CHAKRABORTY, K., A. Phase Transformation of Kaolinite Clay. London: Springer, 2014. ISBN 978-81-322-1153-2.

Recommended literature:

[1] KOLLER, A. Structure and Properties of Ceramics. Amsterdam: Elsevier, 1994. ISBN 0-444-98719-3. [2] ROUTSCHKA, G. Refractory materials: Basics – Structures –Properties. 2nd Ed. Essen: Vulkan Verlag, 2004. ISBN 3-8027-3154-9. [3] SURENDRANATHEN, A., O. An Introduction to Ceramic and Refractories. New York: Taylor & Francis Group, 2015. ISBN 978-1-4822-2044-5.

Way of continuous check of knowledge in the course of semester

Written test and oral exam.

E-learning

Other requirements

no more requirements

Prerequisities

Subject has no prerequisities.

Co-requisities

Subject has no co-requisities.

Subject syllabus:

• Introduction to thermodynamics. The first thermodynamic law, expression for defined process conditions. Enthalpy, reaction heat, standard states. • Calculation of reaction heat from enthalpy of formation. Calculation of reaction heat from combustion and dissolving enthalpy. • The thermal capacity of substances. Dependence of reaction heat on temperature. • The second thermodynamic law. Entropy. Linked formulation of 1. and 2. thermodynamic law. • Dependence of entropy on state variables. Change of entropy during the phase changes and chemical reactions. Energetic function F and G and their dependence on state variables. • Conditions of thermodynamic balance for specific systems. Partial molar quantities, Gibbs-Duhem equation. • Balance in one-component system, Clapeyron equal. Clausius-Clapeyron equal, application. • Equal constant of chemical reaction, its dependence on temperature. • Gibbs phase law, application. Thermodynamic analyse of two-component system, binary phase diagrams. • Rules of representation 3- and 4-component systems, ternary phase diagrams. • Richardson-Jeffes’s diagram, mutual stability of oxides. • Reduction of oxides by hydrogen and carbon oxide. Reduction of oxides by carbon. Stability of oxides with different partial pressure of oxygen.

Conditions for subject completion

Full-time form (validity from: 2019/2020 Winter semester)
Task nameType of taskMax. number of points
(act. for subtasks)
Min. number of pointsMax. počet pokusů
Credit and Examination Credit and Examination 100 (100) 51
        Credit Credit 25  13
        Examination Examination 75  38 3
Mandatory attendence participation: Min. 80 % attendance on exercise.

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Conditions for subject completion and attendance at the exercises within ISP: Completion of all mandatory tasks within individually agreed deadlines.

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Occurrence in study plans

Academic yearProgrammeBranch/spec.Spec.ZaměřeníFormStudy language Tut. centreYearWSType of duty
2023/2024 (N0713A070004) Thermal energetics engineering TKM K Czech Ostrava 1 Compulsory study plan
2023/2024 (N0713A070004) Thermal energetics engineering TKM P Czech Ostrava 1 Compulsory study plan
2022/2023 (N0713A070004) Thermal energetics engineering TKM P Czech Ostrava 1 Compulsory study plan
2022/2023 (N0713A070004) Thermal energetics engineering TKM K Czech Ostrava 1 Compulsory study plan
2021/2022 (N0713A070004) Thermal energetics engineering TKM P Czech Ostrava 1 Compulsory study plan
2021/2022 (N0713A070004) Thermal energetics engineering TKM K Czech Ostrava 1 Compulsory study plan
2020/2021 (N0713A070004) Thermal energetics engineering TKM K Czech Ostrava 1 Compulsory study plan
2020/2021 (N0713A070004) Thermal energetics engineering TKM P Czech Ostrava 1 Compulsory study plan
2019/2020 (N0713A070004) Thermal energetics engineering TKM P Czech Ostrava 1 Compulsory study plan
2019/2020 (N0713A070004) Thermal energetics engineering TKM K Czech Ostrava 1 Compulsory study plan

Occurrence in special blocks

Block nameAcademic yearForm of studyStudy language YearWSType of blockBlock owner

Assessment of instruction



2020/2021 Summer