651-0926/02 – Theory of metallurgical processes (TMP)
Gurantor department | Department of Chemistry and Physico-Chemical Processes | Credits | 10 |
Subject guarantor | prof. Ing. Jana Dobrovská, CSc. | Subject version guarantor | prof. Ing. Jana Dobrovská, CSc. |
Study level | postgraduate | Requirement | Choice-compulsory type B |
Year | | Semester | winter + summer |
| | Study language | English |
Year of introduction | 2022/2023 | Year of cancellation | |
Intended for the faculties | FMT | Intended for study types | Doctoral |
Subject aims expressed by acquired skills and competences
The aim of the course is to deepen the basic knowledge of the student acquired in the previous study in the field of theory of metallurgical processes with a focus on modern directions of development, especially in high-temperature processes.
After completing the course, the student will have deeper knowledge in the field of thermodynamics and kinetics of technological processes with a focus on metallurgy. He will be able to apply the acquired theoretical principles in technological practice.
Teaching methods
Lectures
Individual consultations
Summary
The selection of chapters for thorough study will be made on the basis of the focus of the student's dissertation.
Compulsory literature:
Gupta Ch. K. Chemical Metallurgy: Principles and Practice. WILEY-VCH Verlag GmbH & Co. KGaA, 2003, ISBN: 3-527-30376-6
Recommended literature:
Way of continuous check of knowledge in the course of semester
Oral examination with written preparation according to the study and examination regulations for study in doctoral study programs; part of the evaluation is the previous submission of a written work on the chosen topic
E-learning
Other requirements
Short seminar work on a chosen topic.
Prerequisities
Subject has no prerequisities.
Co-requisities
Subject has no co-requisities.
Subject syllabus:
Thermodynamics, kinetics and explanation of the mechanism of metallurgical reactions.
Thermal dissociation of inorganic compounds. Indirect reduction of oxides, reduction diagrams, technical significance of reduction diagrams of iron oxides. Boudouard reaction and its industrial application. Direct reduction of oxides, reduction diagrams, direct reduction of iron oxides.
Topochemical reactions, thermodynamics of new phase nuclei in the old phase.
Reduction mechanism, Jander's equation. Kinetics of metal oxidation.
Fundamentals of the theory of molten metals, structure and physical properties of molten metals. Crystallization. Homogeneous and heterogeneous nucleation.
Interaction of gases with solid and molten metal, dependence of gas solubility on selected factors. Conditions for the exclusion of gas bubbles from metal melts. Methods for reducing dissolved gases in metals.
Molten slags, basic concepts, classification of ions in slags, ionic potential, alkalinity of slags. Physicochemical properties of slags and methods of studying slags. Theory and models of ionic melts, thermodynamic description of an ideal and real ionic solution.
Physico-chemical analysis of refining processes. Refining reactions - desulphurization, dephosphorization, deoxidation in terms of ideas about slag theory.
Non-metallic phases in metal. Inclusions, origin and floatation, thermodynamic and kinetic factors of inclusion growth.
Modern trends in metallurgy.
Conditions for subject completion
Occurrence in study plans
Occurrence in special blocks
Assessment of instruction
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