651-0977/02 – Advanced Inorganic Chemictry (PACH)
| Gurantor department | Department of Chemistry and Physico-Chemical Processes | Credits | 10 |
| Subject guarantor | prof. Ing. Vlastimil Matějka, Ph.D. | Subject version guarantor | prof. Ing. Vlastimil Matějka, Ph.D. |
| Study level | postgraduate | Requirement | Choice-compulsory type B |
| Year | | Semester | winter + summer |
| | Study language | English |
| Year of introduction | 2022/2023 | Year of cancellation | |
| Intended for the faculties | FMT | Intended for study types | Doctoral |
Subject aims expressed by acquired skills and competences
Deepening of knowledge about the relationship between chemical bond, structure and properties of compounds and substances, application of this knowledge to new perspective inorganic materials.
Teaching methods
Lectures
Individual consultations
Summary
General inorganic chemistry - the relationship between chemical bonding, structure and physical and chemical properties of inorganic compounds. Bonds and stereochemistry of covalent compounds, solid metallic and ionic substances. Thermodynamic stability of oxidation states. Reactions in ionic, oxide and metal melts. Acidity, alkalinity and oxidation capacity of oxide melts. Synthesis of inorganic compounds in molten salts. Preparation and characterization of inorganic nanomaterials. Chemistry of metallic f-elements, use of lanthanides in metallurgy.
Compulsory literature:
Recommended literature:
Way of continuous check of knowledge in the course of semester
Oral examination.
E-learning
Other requirements
There are no additional requirements for students.
Prerequisities
Subject has no prerequisities.
Co-requisities
Subject has no co-requisities.
Subject syllabus:
1. General inorganic chemistry. Trends in properties of s, p, d, f elements and their compounds.
2. Binding and stereochemistry of covalent compounds. Bonds and structure of solid metallic and ionic substances.
3. Acids, bases and ions in aqueous solutions. Oxidation, reduction and thermal properties of inorganic compounds.
4. Thermodynamic stability of oxidation states - Frost diagrams.
5. Reactions in non-aqueous media - ionic, oxide and metal melts.
6. Acid-base and oxidation-reduction reactions in molten salts and oxide melts. Acidity, alkalinity and oxidation capacity of oxide melts.
7. Synthesis of inorganic compounds in molten salts.
8. Preparation and characterization of inorganic nanomaterials.
9. Chemistry of metallic f-elements. Inorganic compounds of 4f-elements (lanthanides) and selected 5f-elements (Th, Pa, U, Pu), their similarity to elements of 4th, 5th and 6th groups.
10. The use of lanthanides in metallurgy with regard to the stability of their oxides and sulfides.
Conditions for subject completion
Occurrence in study plans
Occurrence in special blocks
Assessment of instruction
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