651-2005/02 – Organic Chemistry (OCh)

Gurantor departmentDepartment of Chemistry and Physico-Chemical ProcessesCredits6
Subject guarantordoc. Ing. Lenka Kulhánková, Ph.D.Subject version guarantordoc. Ing. Lenka Kulhánková, Ph.D.
Study levelundergraduate or graduateRequirementCompulsory
Year2Semesterwinter
Study languageCzech
Year of introduction2022/2023Year of cancellation
Intended for the facultiesFMTIntended for study typesBachelor
Instruction secured by
LoginNameTuitorTeacher giving lectures
KUL37 doc. Ing. Lenka Kulhánková, Ph.D.
PAV33 Ing. Jan Pavelka, ING.PAED.IGIP
Extent of instruction for forms of study
Form of studyWay of compl.Extent
Full-time Credit and Examination 3+3

Subject aims expressed by acquired skills and competences

- to define the binding properties of carbon, - to detect intermolecular interactions and their effect on the melting point, the boiling point and the solubility of organic compounds, - to define the separation of organic compounds into groups, - to know the nomenclature of organic compounds, - to describe the relationship between structure and properties of organic compounds, - to describe the physical properties of hydrocarbons and their derivatives, - to describe the reactivity of hydrocarbons and their derivatives, - to describe the most common hydrocarbons and their derivatives, - to define the basic groups, structure, properties and methods of preparation for polymeric substances. Acquired knowledge: - the ability to define a core group of organic compounds, - the ability to determine the name of organic compounds, - the ability to characterize the relationship between structure and properties of organic substances, - the ability to characterize the reactions of organic compounds. Acquired skills: - the ability to apply theoretical knowledge points to selected technological processes, - the ability to use basic laboratory techniques (filtration, recrystallization, distillation, decantation, cooling, etc.), - the ability to use basic methods of preparing organic compounds (esterification, diazotization, etc.).

Teaching methods

Lectures
Tutorials
Experimental work in labs

Summary

The review of the key principles of the organic chemistry, modern methods of organic synthesis and organic analysis, as well as extension of the knowledge about the most important groups of organic compounds.

Compulsory literature:

MCMURRY, John. Organic chemistry. 6th ed. Belmont: Thomson Brooks/Cole, c2004. ISBN 0-534-38999-6.

Recommended literature:

SOLOMONS, T. W. Graham a Craig B. FRYHLE. Organic chemistry [CD-ROM]. 8th ed. Hoboken: Wiley, c2004. ISBN 0-471-41799-8.

Way of continuous check of knowledge in the course of semester

Credit test, written and oral exam.

E-learning

Other requirements

Passing the credit tests. Passing of the desired number of laboratory exercises and handing of laboratory protocols.

Prerequisities

Subject has no prerequisities.

Co-requisities

Subject has no co-requisities.

Subject syllabus:

Lectures 1. Introduction into the organic chemistry. History of organic chemistry. Bonding power of carbon (molecular orbitals,  and  bond, energy of bond, polarity of bond, hybridization, effects of electron). Relation between the structure and the properties of substances. Intermolecular interaction (van der Waals interaction, interaction of dipole, hydrogen bonds) and their influence on the melting temperature, boiling temperature and solubility. 2. Principles of stereochemistry of organic compounds. Drawing organic molecules (types of formulae, projection, models, 3D-shape of molecules). Polymerism and isomerism (constitutional, geometric, enantiomeric). The conformation of organic compounds. 3. Chemical reactions of organic compounds. Classification of organic reactions. Homolysis and heterolysis. Electrophilic and nucleophilic agents. Aliphatic and alicyclic hydrocarbons. Nomenclature of saturated hydrocarbons. Radical substitution. Cracking (catalyzed and uncatalyzed) and isomerization. Fischer-Tropsch synthesis. Resources of hydrocarbons and their application. 4. Unsaturated hydrocarbons. Radical and ion addition on double bond. Elimination reactions. Resources of unsaturated hydrocarbons and their industrial application. 5. Aromatic compounds. Delocalization of  electrons. Electrophilic aromatic substitution (nitration, sulfonation, alkylation, acylation, halogenation) and others reactions. Resources of aromates and their industrial application. Toxicity of polyaromatic compounds. 6. Derivatives of hydrocarbons. Halogen derivatives. Physical properties, toxicity and application. Synthesis and important reactions. 7. Nitrogen derivatives of hydrocarbons (nitrocompounds, amines, diazonium salts, azocompounds). Physical properties, toxicity and application. Synthesis and important reactions. Alkaloids. 8. Sulfur derivatives of hydrocarbons (thioalcohols and thiophenols, sulfides, sulfonic acids). Physical properties and application. Synthesis and important reactions. Detergents. 9. Oxygen derivatives of hydrocarbons. Alcohols and phenols. Ethers. Physical properties, toxicity and application. Synthesis and important reactions. 10. Carbonyl compounds (aldehydes and ketones). Physical properties, toxicity and application. Synthesis and important reactions. Organometallic compounds. Reactivity, toxicity and application. Grignard reagents and their reactions. 11. Carboxylic acids. Physical properties and application. Synthesis and important reactions (acidity versus structure, neutralization, esterification, decarboxylation). 12. Substitution derivatives of carboxylic acids. Halogen-, Hydroxy-, Oxo, and Amino-acids. Physical properties and application. Synthesis and important reactions. 13. Functional derivatives of carboxylic acids. Acyl halides. Anhydrides. Esters. Amides. Nitriles. Physical properties, toxicity and application. Synthesis and important reactions. Derivatives of carbonic acid (phosgene, urea and their sulfur analogues). 14. Polymers (types, structure, properties, basic reactions of polymers preparation, overview of technically most important polymers). Theoretical tutorials - Introductory information (schedule of the seminar, the conditions for obtaining credit and recommended literature). Entering of seminar papers. Bonding power of carbon. - Structure, formula, model. Inference of molecular formula, rational formula and structural formula. Determination of isomerism type for given compounds. - Nomenclature of organic compounds. - Nomenclature of organic compounds. - Nomenclature of organic compounds. - Nomenclature of organic compounds. - Nomenclature of organic compounds. Experimental work in labs - Work safety in the laboratory, introduction to laboratory exercises, basic informations about exercises and requirements for laboratory protocols processing. Preparation of iodoform. - Preparation of 1-nitronaphtalene. - Preparation of 4-nitroaniline. - Preparation of para red. - Preparation of fumaric acid. - Preparation of acetylsalicylic acid. - Preparation of ethyl formate.

Conditions for subject completion

Full-time form (validity from: 2022/2023 Winter semester)
Task nameType of taskMax. number of points
(act. for subtasks)
Min. number of pointsMax. počet pokusů
Credit and Examination Credit and Examination 100 (100) 51
        Credit Credit 30  16
        Examination Examination 70 (70) 35 3
                Písemná zkouška Written examination 40  21
                Ústní zkouška Oral examination 30  14
Mandatory attendence participation: Min. 80% mandatory participation in seminars. Completion of laboratory tasks, submission of protocols. Passing a tests.

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Conditions for subject completion and attendance at the exercises within ISP: Completion of all mandatory tasks within individually agreed deadlines.

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Occurrence in study plans

Academic yearProgrammeBranch/spec.Spec.ZaměřeníFormStudy language Tut. centreYearWSType of duty
2025/2026 (B0712A130004) Chemical and environmental engineering P Czech Ostrava 2 Compulsory study plan
2024/2025 (B0712A130004) Chemical and environmental engineering P Czech Ostrava 2 Compulsory study plan
2023/2024 (B0712A130004) Chemical and environmental engineering P Czech Ostrava 2 Compulsory study plan
2022/2023 (B0712A130004) Chemical and environmental engineering P Czech Ostrava 2 Compulsory study plan

Occurrence in special blocks

Block nameAcademic yearForm of studyStudy language YearWSType of blockBlock owner

Assessment of instruction



2023/2024 Winter
2022/2023 Winter