651-3325/02 – Intercalated nanomaterials (IN)
| Gurantor department | Department of Chemistry and Physico-Chemical Processes | Credits | 2 |
| Subject guarantor | prof. Ing. Vlastimil Matějka, Ph.D. | Subject version guarantor | prof. Ing. Vlastimil Matějka, Ph.D. |
| Study level | undergraduate or graduate | Requirement | Compulsory |
| Year | 1 | Semester | summer |
| | Study language | English |
| Year of introduction | 2022/2023 | Year of cancellation | |
| Intended for the faculties | FMT | Intended for study types | Follow-up Master |
Subject aims expressed by acquired skills and competences
The aim of the subject is to provide the information about the intercalated materials, their properties and utilization. Student will understand: i) the issues related to the intercalation chemistry, ii) the methods used for the characterization of the products of the intercalation reactions, iii) intercalation of layered silicates and iv) pillared materials. Based on the knowledge obtained within the lectures the student is able to evaluate the application potential of intercalated and pillared materials.
Teaching methods
Lectures
Summary
The subject relates to the students knowledge in the field of chemistry, physics and chemistry of solid phase and layered materials. At the beginning the lectures are focused on the explanation of the terms layered materials, intercalation and subdivision of the intercalated materials. Next part concerns with the intercalation chemistry with attention to the properties of the intercalated materials their host lattices, itercalation reactions and the methods used for the intercalation. Following lectures deal with the methods used for the study of the structure, texture and optical properties of the intercalated materials. The topics related to cation exchange phenomenon in the layered phylosilicates, organo-clay complexes, preparation and the properties of clay/(conductive polymer) composites preparation and the properties of photofuncionalized intercalated clay materials are expressed during next lectures. The introduction to pillared and porous clay heterostructures and the overview of the application potential of intercalated and pillared materials are studied in the last part of the lectures.
Compulsory literature:
Recommended literature:
Additional study materials
Way of continuous check of knowledge in the course of semester
Oral exam.
E-learning
Other requirements
Elaboration of project on given topic.
Prerequisities
Subject has no prerequisities.
Co-requisities
Subject has no co-requisities.
Subject syllabus:
1. Layered materials, intercalation, types of the intercalated materials
2. Properties of the intercalated materials, host lattices, intercalation reactions, methods used for the intercalation.
3. The methods used for the study of the structure of the intercalated materials.
4. The methods used for the study of the texture of the intercalated materials.
5. The methods for the study of the optical properties of the intercalated materials.
6. Cation exchange capacity of clay minerals.
7. Intercalation of clay minerals, organo-clay complexes.
8. Preparation and properties of clay/polymer composites.
9. Preparation and the properties of clay/(conductive polymer) composites
10. Preparation and the properties of photofunctionable intercalated clay minerals.
11. Pillared and porous clay heterostructures.
12. Other types of the intercalated materials.
13. The examples of the practical utilization of the intercalated materials.
14. Presentation of the students’ projects.
Conditions for subject completion
Occurrence in study plans
Occurrence in special blocks
Assessment of instruction