9360-0104/02 – Physical chemistry exercises (FCHLC)

Gurantor departmentCNT - Nanotechnology CentreCredits4
Subject guarantordoc. Mgr. Kateřina Mamulová Kutláková, Ph.D.Subject version guarantordoc. Mgr. Kateřina Mamulová Kutláková, Ph.D.
Study levelundergraduate or graduateRequirementCompulsory
Year2Semesterwinter
Study languageCzech
Year of introduction2019/2020Year of cancellation
Intended for the facultiesUSP, FMTIntended for study typesBachelor
Instruction secured by
LoginNameTuitorTeacher giving lectures
LAC10 Ing. Zdenek Lacný
MAM02 doc. Mgr. Kateřina Mamulová Kutláková, Ph.D.
OLS0035 Ing. Eva Olšovská
PEI0007 Mgr. Pavlína Peikertová, Ph.D.
SMI0073 Ing. Julie Smijová
CIH050 Ing. Michaela Tokarčíková, Ph.D.
Extent of instruction for forms of study
Form of studyWay of compl.Extent
Full-time Graded credit 0+4

Subject aims expressed by acquired skills and competences

In the course of the practical exercises the student reaches the ability to find suitable method for the measurement of selected physicochemical properties, the practical courses also lead to achieve the understanding of the principles of the selected methods and obtaining the skills in the field of the interpretation of the experimental data.

Teaching methods

Experimental work in labs

Summary

The Physical chemistry exercises in practical level complements the subject Chemistry II – Physical Chemistry. Within the frame of the subject students are getting acquainted with the following topics of physical chemistry measurements: • Measurement of the density of the liquid and solid samples and determination of the surface tension. • Viscosity measurements of the liquids and its dependency on the temperature. • Determination of the partial molar volumes. • Determination of the heat capacity of the solid samples. • Phase equilibrium in three components system. • Extraction, determination of the distribution ratio. • Determination of the molecular weight using ebulioscopic and cryoscopic technique. • Conductivity measurement of the electrolytes, its dependency on electrolyte concentration and temperature. •Determination of the dissociation constant for week acids based on the measurement of the conductivity. Evaluation of the solubility product. • Determination of the molar absorption coefficient. Evaluation of the band gap energy of the semiconductors in powder form. • Rate of the chemical reactions, evaluation of the specific rate constant of the pseudo-first order chemical reaction.

Compulsory literature:

BALL, David Warren. Physical chemistry. Belmont: Brooks/Cole, c2003. ISBN 0-534-26658-4. ATKINS, P. W. The elements of physical chemistry. 2nd ed. Oxford: Oxford University Press, c1996. ISBN 0-19-855953-4.

Recommended literature:

ATKINS, P. W a Julio DE PAULA. Atkins' Physical chemistry. 10th ed. Oxford: Oxford University Press, c2014. ISBN 978-0-19-969740-3.

Way of continuous check of knowledge in the course of semester

Combined oral and written form. The study results are verified continuously in the exercises. Score > 50 % is required for passing the exercises.

E-learning

Other requirements

For this subject other requirements for student are not determined.

Prerequisities

Subject has no prerequisities.

Co-requisities

Subject has no co-requisities.

Subject syllabus:

1. Electrolysis, conductivity of solutions. Conductometric titrations. 2. Partial molar volume. Determination of partial molar volumes. 3. Viscosity. Measurement of viscosity. 4. Heat capacity, heat of combustion, heat of dilution. 5. Distillation, extraction. Determination of the distribution ratio. 6. Density of solid and liquid mater. Measurement of density. 7. Surface tension. 8. Dissociation constant, solubility product. 9. Evaluation of band gap (Eg), UV–VIS diffuse reflectance spectroscopy. 10. Evaluation of photodegradation activity. 11. Determination of the molar absorption coefficient. 12. Ebullioscopy, cryoscopy. Determination of the molecular weight using ebulioscopic and cryoscopic technique. 13. Specific rate constant of chemical reactions, activation energy. 14. Calorimetry.

Conditions for subject completion

Full-time form (validity from: 2019/2020 Winter semester)
Task nameType of taskMax. number of points
(act. for subtasks)
Min. number of pointsMax. počet pokusů
Graded credit Graded credit 100  51 3
Mandatory attendence participation: You need 100% attendance to sit for your exercises. You need to apply for your sick leave.

Show history

Conditions for subject completion and attendance at the exercises within ISP:

Show history

Occurrence in study plans

Academic yearProgrammeBranch/spec.Spec.ZaměřeníFormStudy language Tut. centreYearWSType of duty
2023/2024 (B0719A270001) Nanotechnology P Czech Ostrava 2 Compulsory study plan
2022/2023 (B0719A270001) Nanotechnology P Czech Ostrava 2 Compulsory study plan
2021/2022 (B0719A270001) Nanotechnology P Czech Ostrava 2 Compulsory study plan
2020/2021 (B0719A270001) Nanotechnology P Czech Ostrava 2 Compulsory study plan
2019/2020 (B0719A270001) Nanotechnology P Czech Ostrava 2 Compulsory study plan

Occurrence in special blocks

Block nameAcademic yearForm of studyStudy language YearWSType of blockBlock owner

Assessment of instruction



2020/2021 Winter