9360-0152/01 – Molecular and supramolecular nanomachines (MOLNM)

Gurantor departmentCNT - Nanotechnology CentreCredits4
Subject guarantordoc. Ing. Jonáš Tokarský, Ph.D.Subject version guarantordoc. Ing. Jonáš Tokarský, Ph.D.
Study levelundergraduate or graduateRequirementOptional
Year2Semestersummer
Study languageCzech
Year of introduction2010/2011Year of cancellation
Intended for the facultiesUSPIntended for study typesFollow-up Master
Instruction secured by
LoginNameTuitorTeacher giving lectures
CAP01 prof. RNDr. Pavla Čapková, DrSc.
TOK006 doc. Ing. Jonáš Tokarský, Ph.D.
Extent of instruction for forms of study
Form of studyWay of compl.Extent
Full-time Credit and Examination 2+0

Subject aims expressed by acquired skills and competences

Student will be able to: define the term nanomachine classify and characterize various types of nanomachines discuss methods of controlling nanomachines and monitoring their movement characterize basic concepts of supramolecular chemistry, coordination chemistry and molecular topology predict the properties of nanomachines according to the structure discuss the principles of syntheses of nanomachines demonstrate suitable types of nanomachines for specific applications

Teaching methods

Lectures
Seminars
Individual consultations

Summary

Student is acquainted with the issue of nanomachines - a relatively new and increasingly evolving area of nanotechnology. An unconventional view of molecular and supramolecular structures is presented in terms of their properties and functionality, and the knowledge of students in chemistry and physics of nanomaterials is further extended to understand the principles of nanomachines and the methods of controlling their intended motion. Wide range of nanomachines, from simple synthetic functional components to complex nanomachines based on synthetic and natural supramolecular structures is presented in this course. The first practical applications of the nanomachines are also discussed. The seminar is supplemented by many examples from the scientific literature.

Compulsory literature:

GÓMEZ-LÓPEZ, M. and J.F. STODDART. Chapter 3 – Molecular and supramolecular nanomachines. NALWA, H.S. Handbook of Nanostructured Materials and Nanotechnology: Volume 5. San Diego: Academic Press, 2000, pp. 225–275. ISBN 978-0-12-513760-7. BENNISTON, A. C. and P. R. MACKIE. Chapter 4 – Functional nanostructures incorporating responsive modules. NALWA, H.S. Handbook of Nanostructured Materials and Nanotechnology: Volume 5. San Diego: Academic Press, 2000, pp. 277-331. ISBN 978-0-12-513760-7. MULLER, A.W.J. Were the first organisms heat engines? A new model for biogenesis and the early evolution of biological energy conversion. Progress in Biophysics and Molecular Biology. 1995, vol. 63, no. 2, pp. 193-231. DOI: 10.1016/0079-6107(95)00004-7.

Recommended literature:

DREXLER, K.E. Engines of Creation: The Coming Era of Nanotechnology. 2nd ed. New York: Anchor Press, 1987. ISBN 978-0385199735. WANG, J. Nanomachines: Fundamentals and Applications. 1st ed. Weinheim: Wiley-VCH, 2013. ISBN: 978-3-527-33120-8. BALZANI, V., A. CREDI and M. VENTURI. Molecular devices and machines. Nano Today. 2007, vol. 2, no. 2, pp. 18-25. DOI: 10.1016/S1748-0132(07)70055-5. SAUVAGE, J.P., J.P. COLLIN, S. DUROT, J. FREI, V. HEITZ, A. SOUR and C. TOCK. From chemical topology to molecular machines. Comptes Rendus Chimie. 2010, vol. 13, no. 3, pp. 315-328. DOI: 10.1016/j.crci.2009.10.008. SEEMAN, N.C. From genes to machines: DNA nanomechanical devices. Trends in Biochemical Sciences. 2005, vol. 30, no. 3, pp.119-125. DOI: 10.1016/j.tibs.2005.01.007.

Way of continuous check of knowledge in the course of semester

E-learning

Další požadavky na studenta

For this subject other requirements for student are not determined.

Prerequisities

Subject has no prerequisities.

Co-requisities

Subject has no co-requisities.

Subject syllabus:

Electronic properties of molecular systems. Basics of molecular spectroscopy, Jablonski diagram, absorption, vibrational relaxation, intrinsic conversion, phosphorescence, fluorescence, optical activity. 2. Conformational changes and stability of molecular structures. Changes of conformation induced photochemically and electrochemically. Interconversion between two conformers - rotation of functional groups. Molecular switches, molecular rotors and molecular brakes. Utilization of azobenzenes as molecular switches. Photochromic behavior of spiropyranes. 3. Functional units based on supramolecular systems. Photo inducible molecular switches based on crown ethers–azobenzenes–alkali metals complexes. Fluorescence of molecular complexes. Electrochemically controlled supramolecular switches. Photo inducible supramolecular switches. pH-controlled supramolecular switches. 4. Organic-inorganic hybrid nanostructures as a functional groups. Optically active molecules anchored on layered silicates. Changes of spectral characteristics of dye molecules anchored on inorganic substrates. Nanoreactors based on intercalated layered silicates.

Conditions for subject completion

Full-time form (validity from: 2010/2011 Winter semester)
Task nameType of taskMax. number of points
(act. for subtasks)
Min. number of points
Exercises evaluation and Examination Credit and Examination 100  51
        Exercises evaluation Credit  
        Examination Examination  
Mandatory attendence parzicipation:

Show history

Occurrence in study plans

Academic yearProgrammeField of studySpec.FormStudy language Tut. centreYearWSType of duty
2019/2020 (N3942) Nanotechnology (3942T001) Nanotechnology P Czech Ostrava 2 Optional study plan
2018/2019 (N3942) Nanotechnology (3942T001) Nanotechnology P Czech Ostrava 2 Optional study plan
2017/2018 (N3942) Nanotechnology (3942T001) Nanotechnology P Czech Ostrava 2 Optional study plan
2016/2017 (N3942) Nanotechnology (3942T001) Nanotechnology P Czech Ostrava 2 Optional study plan
2015/2016 (N3942) Nanotechnology (3942T001) Nanotechnology P Czech Ostrava 2 Optional study plan
2014/2015 (N3942) Nanotechnology (3942T001) Nanotechnology P Czech Ostrava 2 Optional study plan
2014/2015 (N3942) Nanotechnology P Czech Ostrava 2 Optional study plan
2013/2014 (N3942) Nanotechnology (3942T001) Nanotechnology P Czech Ostrava 2 Optional study plan
2012/2013 (N3942) Nanotechnology (3942T001) Nanotechnology P Czech Ostrava 2 Optional study plan
2011/2012 (N3942) Nanotechnology (3942T001) Nanotechnology P Czech Ostrava 2 Optional study plan
2010/2011 (N3942) Nanotechnology (3942T001) Nanotechnology P Czech Ostrava 2 Optional study plan

Occurrence in special blocks

Block nameAcademic yearForm of studyStudy language YearWSType of blockBlock owner
USP 2014/2015 Full-time Czech Optional USP - University Study Programmes stu. block
USP 2013/2014 Full-time Czech Optional USP - University Study Programmes stu. block
USP 2012/2013 Full-time Czech Optional USP - University Study Programmes stu. block