9360-0199/01 – Chemical kinetics and catalysis (CHK)

Gurantor departmentCNT - Nanotechnology CentreCredits3
Subject guarantorprof. Ing. Jana Seidlerová, CSc.Subject version guarantorprof. Ing. Jana Seidlerová, CSc.
Study levelundergraduate or graduateRequirementChoice-compulsory type A
Year2Semestersummer
Study languageCzech
Year of introduction2019/2020Year of cancellation
Intended for the facultiesFMTIntended for study typesFollow-up Master
Instruction secured by
LoginNameTuitorTeacher giving lectures
MAM02 Mgr. Kateřina Mamulová Kutláková, Ph.D.
MAT27 doc. Ing. Vlastimil Matějka, Ph.D.
SEI40 prof. Ing. Jana Seidlerová, CSc.
Extent of instruction for forms of study
Form of studyWay of compl.Extent
Full-time Credit and Examination 2+1

Subject aims expressed by acquired skills and competences

The aim of the course is to deepen the students’ knowledge in the field of chemical kinetics by expanding the theoretical knowledge to the solving of more complicated reactions such as simultaneous or chain reactions in various environments. The effect of the environment on reaction rate as well as mathematical expression of this effect in basic reaction rate equations. During the lectures, the students are going to get acquainted with the importance and principals of catalysis, both homogeneous and heterogeneous, using practical examples. At the same time, the students are going to use their acquired theoretical knowledge while working on practical assignments in the subsequent laboratory class.

Teaching methods

Lectures
Tutorials
Experimental work in labs

Summary

Předmět je zaměřen na získání detailních znalostí z oblasti chemické kinetiky a katalýzy. K jeho studiu je zapotřebí základních znalostí formální chemické kinetiky a teorií mechanismu chemických reakcí. Po jeho absolvování budou studenti schopni aplikovat své znalosti na praktické příklady, bude schopen plánovat experiment s cílem stanovení kinetických parametrů chemické reakce. Výsledky experimentu bude umět interpretovat.

Compulsory literature:

ATKINS, P., W., Paula, J.: Atkin´s Physical Chemistry. Oxford UP 2003, ISBN 0198792859. SANTEN, R. A.: ed. Catalysis: an integrated approach. 2nd, rev. and enl. ed. Amsterdam: Elsevier, 1999. ISBN 0-444-82963-6.

Recommended literature:

https://www.khanacademy.org/science/chemistry/chem-kinetics DE LASA, Hugo I., SERRANO-ROSALES, B. and SALAICES, M.. Photocatalytic reaction engineering. New York: Springer, c2005. ISBN 0-387-23450-0.

Way of continuous check of knowledge in the course of semester

Written and oral.

E-learning

Other requirements

Write laboratory report.

Prerequisities

Subject has no prerequisities.

Co-requisities

Subject has no co-requisities.

Subject syllabus:

LECTURES: 1. Introduction, reaction rate and its description by formal mechanism, simple chemical reactions 2. Formal kinetics of complex reactions (simultaneous, reversible, lateral, sequential and chain reactions) 3. Formal kinetics of chain reaction and polycondenzation 4. Experimental methods of chemical kinetics, measurement of reaction rate, evaluation of measurements 5. Mechanism of elementary action I - theory of active collisions 6. Mechanism of elementary action II - theory of absolute reaction velocities, 7. New theory of mechanism description, advantages and shortcomings of individual theories 8. Reactions in the gas phase, reactions in the liquid phase, precipitation in solution 9. Factors influencing the rate of chemical reaction, environmental impact 10. Chemical reactions in solutions 11. Kinetics of heterogeneous reactions, mechanism, speed determining step 12. Theory of homogeneous catalysis, autocatalysis, examples 13. Heterogeneous catalysis, mechanism, activity of catalysts 14. Photocatalysis, principle and description of mechanism, examples Laboratory exercises 1. Introduction, content of laboratory exercises and requirements for obtaining credit. 2. Determination of the order of reaction in solution by the method of measuring the half-life of the chemical reaction. 3. Determination of velocity constant 4. Determination of activation energy 5. Determination of temperature dependence of activation energy 6. Determination of photocatalytic reaction rate constant Exercises will be completed with a blackboard exercise with theoretical calculations.

Conditions for subject completion

Full-time form (validity from: 2019/2020 Winter semester)
Task nameType of taskMax. number of points
(act. for subtasks)
Min. number of points
Credit and Examination Credit and Examination 100 (100) 51
        Credit Credit 40  25
        Examination Examination 60  30
Mandatory attendence parzicipation: 95 %

Show history

Occurrence in study plans

Academic yearProgrammeField of studySpec.ZaměřeníFormStudy language Tut. centreYearWSType of duty
2021/2022 (N0719A270002) Nanotechnology CH2 P Czech Ostrava 2 Choice-compulsory type A study plan
2020/2021 (N0719A270002) Nanotechnology CH2 P Czech Ostrava 2 Choice-compulsory type A study plan
2019/2020 (N0719A270002) Nanotechnology CH2 P Czech Ostrava 2 Choice-compulsory type A study plan

Occurrence in special blocks

Block nameAcademic yearForm of studyStudy language YearWSType of blockBlock owner