9360-0212/03 – Supramolekulární chemie a design funkčních nanostruktur (SMCH)
| Gurantor department | CNT - Nanotechnology Centre | Credits | 10 |
| Subject guarantor | doc. Ing. Jonáš Tokarský, Ph.D. | Subject version guarantor | doc. Ing. Jonáš Tokarský, Ph.D. |
| Study level | postgraduate | Requirement | Choice-compulsory type B |
| Year | | Semester | winter + summer |
| | Study language | Czech |
| Year of introduction | 2020/2021 | Year of cancellation | |
| Intended for the faculties | FEI, FMT | Intended for study types | Doctoral |
Subject aims expressed by acquired skills and competences
Student will be able to define the term “supramolecular structure“ and other terms from the area of supramolecular chemistry, classify different types of supramolecular structures, discuss the principles of formation and possibilities of using supramolecular structures, predict the host-guest complementarity,
characterize supramolecular structures using molecular simulation.
Teaching methods
Lectures
Individual consultations
Summary
The aim of the course is to introduce the area of supramolecular chemistry together with the structure and use of supramolecular structures. Students will be acquainted with intermolecular interactions, molecular complementarity or the problem of self-organization of supramolecular structures, from simple organic molecules through biomolecules to organo-inorganic intercalates of molecules and layered materials. Various types of supramolecular structures will be illustrated by a number of examples from the literature. Attention will also be paid to the possibilities of using molecular simulation to characterize supramolecular structures.
Compulsory literature:
ARIGA, K. a T. KUNITAKE. Supramolecular Chemistry – Fundamentals and Applications. Berlin, Heidelberg, New York: Springer, 2006. ISBN: 978-3-540-01298-6
FRIESE, V.A. and D.G. KURTH. From coordination complexes to coordination polymers through self-assembly. Current Opinion in Colloid & Interface Science. 2009, vol. 14, no. 2, pp. 81-93. DOI: 10.1016/j.cocis.2008.11.001
HOBZA, P. a R. ZAHRADNÍK. Intermolecular complexes. 1st ed. Prague: Academia, 1988
Recommended literature:
SEEMAN, N.C. From genes to machines: DNA nanomechanical devices. Trends in Biochemical Sciences. 2005, vol. 30, no. 3, pp.119-125. DOI: 10.1016/j.tibs.2005.01.007
ČAPKOVÁ, P. s H. SCHENK. Host–guest complementarity and crystal packing of intercalated layered structures. Journal of Inclusion Phenomena and Macrocyclic Chemistry. 2003, vol. 47, pp. 1-10. DOI: 10.1023/B:JIPH.0000003826.01697.42
Way of continuous check of knowledge in the course of semester
The study results are verified on the basis of elaboration of individual semestral work. Semester is completed by exam (passing score is > 50 %).
E-learning
Other requirements
Written semestral work. Topic of the seminar work is defined by teacher.
Prerequisities
Subject has no prerequisities.
Co-requisities
Subject has no co-requisities.
Subject syllabus:
Intermolecular interactions, their nature and role in supramolecular structure formation, molecular complementarity and recognition.
Inclusion complexes, host molecules capable to accommodate guest molecules, cyclic, dendrimeric, layered types of host structures.
Molecular crystals, polymorphism of molecular crystals, liquid crystals, co-crystals.
Molecular self-assembly of micelles and layers, structure of cell membranes.
Supramolecular structures based on catenanes and rotaxanes.
Supramolecular structures based on biomolecules.
Intercalation chemistry, organo-inorganic supramolecular structures.
Surface modification of inorganic host structures.
Utilizing the process of self assembly on in the formation of new inorganic structures.
Simulation of supramolecular structures using force fields, geometric optimization and dynamics, calculations of host-guest interaction energies.
Conditions for subject completion
Occurrence in study plans
Occurrence in special blocks
Assessment of instruction
Předmět neobsahuje žádné hodnocení.