9360-0212/04 – Supramolekulární chemie a design funkčních nanostruktur (SMCH)

Gurantor departmentCNT - Nanotechnology CentreCredits10
Subject guarantordoc. Ing. Jonáš Tokarský, Ph.D.Subject version guarantordoc. Ing. Jonáš Tokarský, Ph.D.
Study levelpostgraduateRequirementChoice-compulsory type B
YearSemesterwinter + summer
Study languageEnglish
Year of introduction2020/2021Year of cancellation
Intended for the facultiesFMT, FEIIntended for study typesDoctoral
Instruction secured by
LoginNameTuitorTeacher giving lectures
TOK006 doc. Ing. Jonáš Tokarský, Ph.D.
Extent of instruction for forms of study
Form of studyWay of compl.Extent
Full-time Examination 20+0
Part-time Examination 20+0

Subject aims expressed by acquired skills and competences

Student will be able to define the term “supramolecular structure“ and other terms from the area of supramolecular chemistry, classify different types of supramolecular structures, discuss the principles of formation and possibilities of using supramolecular structures, predict the host-guest complementarity, characterize supramolecular structures using molecular simulation.

Teaching methods

Lectures
Individual consultations

Summary

The aim of the course is to introduce the area of supramolecular chemistry together with the structure and use of supramolecular structures. Students will be acquainted with intermolecular interactions, molecular complementarity or the problem of self-organization of supramolecular structures, from simple organic molecules through biomolecules to organo-inorganic intercalates of molecules and layered materials. Various types of supramolecular structures will be illustrated by a number of examples from the literature. Attention will also be paid to the possibilities of using molecular simulation to characterize supramolecular structures.

Compulsory literature:

ARIGA, K. a T. KUNITAKE. Supramolecular Chemistry – Fundamentals and Applications. Berlin, Heidelberg, New York: Springer, 2006. ISBN: 978-3-540-01298-6 FRIESE, V.A. and D.G. KURTH. From coordination complexes to coordination polymers through self-assembly. Current Opinion in Colloid & Interface Science. 2009, vol. 14, no. 2, pp. 81-93. DOI: 10.1016/j.cocis.2008.11.001 HOBZA, P. a R. ZAHRADNÍK. Intermolecular complexes. 1st ed. Prague: Academia, 1988

Recommended literature:

SEEMAN, N.C. From genes to machines: DNA nanomechanical devices. Trends in Biochemical Sciences. 2005, vol. 30, no. 3, pp.119-125. DOI: 10.1016/j.tibs.2005.01.007 ČAPKOVÁ, P. s H. SCHENK. Host–guest complementarity and crystal packing of intercalated layered structures. Journal of Inclusion Phenomena and Macrocyclic Chemistry. 2003, vol. 47, pp. 1-10. DOI: 10.1023/B:JIPH.0000003826.01697.42

Way of continuous check of knowledge in the course of semester

The study results are verified on the basis of elaboration of individual semestral work. Semester is completed by exam (passing score is > 50 %).

E-learning

Other requirements

Written semestral work. Topic of the seminar work is defined by teacher.

Prerequisities

Subject has no prerequisities.

Co-requisities

Subject has no co-requisities.

Subject syllabus:

Intermolecular interactions, their nature and role in supramolecular structure formation, molecular complementarity and recognition. Inclusion complexes, host molecules capable to accommodate guest molecules, cyclic, dendrimeric, layered types of host structures. Molecular crystals, polymorphism of molecular crystals, liquid crystals, co-crystals. Molecular self-assembly of micelles and layers, structure of cell membranes. Supramolecular structures based on catenanes and rotaxanes. Supramolecular structures based on biomolecules. Intercalation chemistry, organo-inorganic supramolecular structures. Surface modification of inorganic host structures. Utilizing the process of self assembly on in the formation of new inorganic structures. Simulation of supramolecular structures using force fields, geometric optimization and dynamics, calculations of host-guest interaction energies.

Conditions for subject completion

Conditions for completion are defined only for particular subject version and form of study

Occurrence in study plans

Academic yearProgrammeField of studySpec.ZaměřeníFormStudy language Tut. centreYearWSType of duty
2021/2022 (P0719D270003) Nanotechnology P English Ostrava Choice-compulsory type B study plan
2021/2022 (P0719D270003) Nanotechnology K English Ostrava Choice-compulsory type B study plan
2021/2022 (P0613D140021) Computational Science P English Ostrava Choice-compulsory type B study plan
2021/2022 (P0613D140021) Computational Science K English Ostrava Choice-compulsory type B study plan
2020/2021 (P0613D140021) Computational Science K English Ostrava Choice-compulsory type B study plan
2020/2021 (P0613D140021) Computational Science P English Ostrava Choice-compulsory type B study plan
2020/2021 (P0719D270003) Nanotechnology P English Ostrava Choice-compulsory type B study plan
2020/2021 (P0719D270003) Nanotechnology K English Ostrava Choice-compulsory type B study plan
2019/2020 (P0613D140021) Computational Science P English Ostrava Choice-compulsory type B study plan
2019/2020 (P0613D140021) Computational Science K English Ostrava Choice-compulsory type B study plan

Occurrence in special blocks

Block nameAcademic yearForm of studyStudy language YearWSType of blockBlock owner